• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

两性离子聚合物用作电子传输层以提高聚合物太阳能电池的性能。

Zwitter-Ionic Polymer Applied as Electron Transportation Layer for Improving the Performance of Polymer Solar Cells.

作者信息

Chen Qiaoyun, Li Zhendong, Dong Bin, Zhou Yi, Song Bo

机构信息

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.

出版信息

Polymers (Basel). 2017 Nov 1;9(11):566. doi: 10.3390/polym9110566.

DOI:10.3390/polym9110566
PMID:30965870
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6419150/
Abstract

A zwitter-ionic polymer poly (sulfobetaine methacrylate) (denoted by PSBMA) was employed as an electron transportation layer (ETL) in polymer solar cells (PSCs) based on poly(3-hexylthiophene) (P3HT):[6,6]-phenyl-C-butyric acid methyl ester (PCBM). PSBMA is highly soluble in trifluoroethanol, showing an orthogonal solubility to the solvent of the active layer in the preparation of multilayered PSCs. Upon introduction of PSBMA, the short circuit current and as a consequence the power conversion efficiency of the corresponding PSCs are dramatically improved, which can be because of the relatively high polarity of PSBMA compared with the other ETLs. This study demonstrated that zwitter-ionic polymer should be a competitive potential candidate of ETLs in PSCs.

摘要

一种两性离子聚合物聚（甲基丙烯酸磺酸甜菜碱）（记为PSBMA）被用作基于聚（3-己基噻吩）（P3HT）：[6,6]-苯基-C-丁酸甲酯（PCBM）的聚合物太阳能电池（PSC）中的电子传输层（ETL）。PSBMA在三氟乙醇中高度可溶，在制备多层PSC时，它与活性层的溶剂具有正交溶解性。引入PSBMA后，相应PSC的短路电流以及功率转换效率都得到了显著提高，这可能是因为与其他ETL相比，PSBMA具有相对较高的极性。这项研究表明，两性离子聚合物应该是PSC中ETL的一个有竞争力的潜在候选者。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/8b30c01f3dae/polymers-09-00566-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/5bd409bad402/polymers-09-00566-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/2823a2c06aee/polymers-09-00566-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/a978a425c265/polymers-09-00566-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/823d579cf24c/polymers-09-00566-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/fa38db05799e/polymers-09-00566-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/8b30c01f3dae/polymers-09-00566-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/5bd409bad402/polymers-09-00566-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/2823a2c06aee/polymers-09-00566-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/a978a425c265/polymers-09-00566-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/823d579cf24c/polymers-09-00566-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/fa38db05799e/polymers-09-00566-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f459/6419150/8b30c01f3dae/polymers-09-00566-g005.jpg

相似文献

1
Zwitter-Ionic Polymer Applied as Electron Transportation Layer for Improving the Performance of Polymer Solar Cells.两性离子聚合物用作电子传输层以提高聚合物太阳能电池的性能。
Polymers (Basel). 2017 Nov 1;9(11):566. doi: 10.3390/polym9110566.
2
High efficiency of poly(3-hexylthiophene)/[6,6]-phenyl C61 butyric acid methyl ester bulk heterojunction solar cells through precrystallining of poly(3-hexylthiophene) based layer.通过聚（3-己基噻吩）基层的预结晶提高聚（3-己基噻吩）/[6,6]-苯基 C61 丁酸甲酯本体异质结太阳能电池的效率。
ACS Appl Mater Interfaces. 2013 Jul 10;5(13):5986-93. doi: 10.1021/am401863r. Epub 2013 Jun 25.
3
A Nonconjugated Zwitterionic Polymer: Cathode Interfacial Layer Comparable with PFN for Narrow-Bandgap Polymer Solar Cells.一种非共轭两性离子聚合物：与 PFN 相当的用于窄带隙聚合物太阳能电池的阴极界面层。
Macromol Rapid Commun. 2018 Jul;39(14):e1700828. doi: 10.1002/marc.201700828. Epub 2018 Mar 8.
4
Imidazole-Functionalized Fullerene as a Vertically Phase-Separated Cathode Interfacial Layer of Inverted Ternary Polymer Solar Cells.咪唑功能化富勒烯作为倒置型三元聚合物太阳能电池的垂直相分离阴极界面层。
ACS Appl Mater Interfaces. 2017 Jan 25;9(3):2720-2729. doi: 10.1021/acsami.6b13461. Epub 2017 Jan 11.
5
Investigation of the Performance of Perovskite Solar Cells with ZnO-Covered PCBM Electron Transport Layer.具有氧化锌覆盖的聚（3-己基噻吩）-苯并三氮唑电子传输层的钙钛矿太阳能电池性能研究。
Materials (Basel). 2023 Jul 18;16(14):5061. doi: 10.3390/ma16145061.
6
In Situ Formation of ZnO in Graphene: A Facile Way To Produce a Smooth and Highly Conductive Electron Transport Layer for Polymer Solar Cells.石墨烯中氧化锌的原位形成：一种制备用于聚合物太阳能电池的光滑且高导电电子传输层的简便方法。
ACS Appl Mater Interfaces. 2015 Jul 29;7(29):16078-85. doi: 10.1021/acsami.5b04555. Epub 2015 Jul 15.
7
Mixed Fullerene Electron Transport Layers with Fluorocarbon Chains Assembling on the Surface: A Moisture-Resistant Coverage for Perovskite Solar Cells.表面带有氟碳链组装的混合富勒烯电子传输层：用于钙钛矿太阳能电池的防潮覆盖层。
ACS Appl Mater Interfaces. 2020 Aug 5;12(31):35081-35087. doi: 10.1021/acsami.0c10074. Epub 2020 Jul 27.
8
Enhanced Performance in Bulk Heterojunction Polymer Solar Cell Using Water Soluble Conjugated Polymer.使用水溶性共轭聚合物提高体异质结聚合物太阳能电池的性能。
J Nanosci Nanotechnol. 2015 Feb;15(2):1683-6. doi: 10.1166/jnn.2015.9305.
9
Efficient polymer solar cells based on poly(3-hexylthiophene) and indene-C₆₀ bisadduct fabricated with non-halogenated solvents.基于聚（3-己基噻吩）和茚-C₆₀双加合物并采用非卤化溶剂制备的高效聚合物太阳能电池。
ACS Appl Mater Interfaces. 2014 Jun 11;6(11):8190-8. doi: 10.1021/am500836u. Epub 2014 May 20.
10
Employing PCBTDPP as an Efficient Donor Polymer for High Performance Ternary Polymer Solar Cells.采用PCBTDPP作为高性能三元聚合物太阳能电池的高效给体聚合物。
Polymers (Basel). 2019 Aug 29;11(9):1423. doi: 10.3390/polym11091423.

引用本文的文献

1
Ultralow-power optoelectronic synaptic transistors based on polyzwitterion dielectrics for in-sensor reservoir computing.基于聚两性离子电介质的超低功耗光电突触晶体管用于传感器内忆阻器计算。
Sci Adv. 2024 Apr 19;10(16):eadn4524. doi: 10.1126/sciadv.adn4524. Epub 2024 Apr 17.

本文引用的文献

1
Novel Two-Dimensional Conjugated Polymer Containing Fluorinated Bithiophene as Donor and Benzoselenodiazole as Acceptor Units with Vinyl-Terthiophene Pendants for Polymer Photovoltaic Cells.用于聚合物光伏电池的新型二维共轭聚合物，含氟化联噻吩作为给体、苯并硒二唑作为受体单元以及带有乙烯基三联噻吩侧链
Polymers (Basel). 2017 Jul 7;9(7):272. doi: 10.3390/polym9070272.
2
Recent Development on Narrow Bandgap Conjugated Polymers for Polymer Solar Cells.用于聚合物太阳能电池的窄带隙共轭聚合物的最新进展
Polymers (Basel). 2017 Jan 28;9(2):39. doi: 10.3390/polym9020039.
3
Comprehensive Study of Sol-Gel versus Hydrolysis-Condensation Methods To Prepare ZnO Films: Electron Transport Layers in Perovskite Solar Cells.
水热/溶胶-凝胶法制备 ZnO 薄膜的综合研究：钙钛矿太阳能电池中的电子传输层
ACS Appl Mater Interfaces. 2017 Aug 9;9(31):26234-26241. doi: 10.1021/acsami.7b04833. Epub 2017 Jul 26.
4
Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells.分子优化使有机太阳能电池的效率超过 13%。
J Am Chem Soc. 2017 May 31;139(21):7148-7151. doi: 10.1021/jacs.7b02677. Epub 2017 May 22.
5
High Performance Small-Molecule Cathode Interlayer Materials with D-A-D Conjugated Central Skeletons and Side Flexible Alcohol/Water-Soluble Groups for Polymer Solar Cells.具有 D-A-D 共轭中心骨架和侧柔性醇/水溶基团的高性能小分子阴极中间层材料，用于聚合物太阳能电池。
ACS Appl Mater Interfaces. 2016 Dec 7;8(48):32823-32832. doi: 10.1021/acsami.6b10900. Epub 2016 Nov 22.
6
Light-Soaking-Free Inverted Polymer Solar Cells with an Efficiency of 10.5% by Compositional and Surface Modifications to a Low-Temperature-Processed TiO Electron-Transport Layer.通过对低温处理的 TiO 电子传输层进行组成和表面改性，实现了无光照浸泡的倒置聚合物太阳能电池，效率达到 10.5%。
Adv Mater. 2017 Jan;29(1). doi: 10.1002/adma.201604044. Epub 2016 Oct 27.
7
Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells.小分子电子受体的能级调制实现聚合物太阳能电池超过 12%的效率。
Adv Mater. 2016 Nov;28(42):9423-9429. doi: 10.1002/adma.201602776. Epub 2016 Sep 8.
8
Realizing Highly Efficient Inverted Photovoltaic Cells by Combination of Nonconjugated Small-Molecule Zwitterions with Polyethylene Glycol.通过非共轭小分子两性离子与聚乙二醇的组合实现高效倒置光伏电池。
ACS Appl Mater Interfaces. 2016 Jul 20;8(28):18593-9. doi: 10.1021/acsami.6b04955. Epub 2016 Jul 11.
9
Fullerene-Free Polymer Solar Cells with over 11% Efficiency and Excellent Thermal Stability.无富勒烯聚合物太阳能电池，光电转换效率超过 11%，热稳定性优异。
Adv Mater. 2016 Jun;28(23):4734-9. doi: 10.1002/adma.201600281. Epub 2016 Apr 9.
10
Solution-Processed 8-Hydroquinolatolithium as Effective Cathode Interlayer for High-Performance Polymer Solar Cells.溶液处理的 8-羟基喹啉酸锂作为高性能聚合物太阳能电池的有效阴极界面层。
ACS Appl Mater Interfaces. 2016 Apr 13;8(14):9254-61. doi: 10.1021/acsami.6b00327. Epub 2016 Apr 1.