Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan.
Chem Commun (Camb). 2011 Feb 21;47(7):2008-10. doi: 10.1039/c0cc04773b. Epub 2010 Dec 23.
A novel p-channel semiconductor pyreno[4,5-a]coronene has been synthesized and characterized. The highly fused π-conjugated framework has a twisted geometry with an excellent on-top cofacial π-π stacking in the crystal structure and with a centroid-to-centroid distance of 3.808 Å. Single-crystal field effect transistors based on the molecule exhibit a high mobility of ~0.89 cm(2) V(-1) s(-1) and an on/off ratio of ~6 × 10(4).
一种新型的 p 型半导体苝[4,5-a]并冠烯已经被合成并进行了表征。该高度稠合的π共轭骨架具有扭曲的几何形状，在晶体结构中具有极好的面对面π-π堆积，并且质心-质心距离为 3.808 Å。基于该分子的单晶场效应晶体管表现出约 0.89 cm(2) V(-1) s(-1)的高迁移率和约 6 × 10(4)的导通/关断比。
