六苯并苯作为刚性模板用于“星状”糖树状聚合物的直接合成。
Hexaphenylbenzene as a rigid template for the straightforward syntheses of "star-shaped" glycodendrimers.
机构信息
Department of Chemistry, Université du Québec à Montréal, P.O. Box 8888, Succ. Centre-Ville Montréal, QC, Canada H3C 3P8.
出版信息
J Org Chem. 2011 Jan 21;76(2):724-7. doi: 10.1021/jo102215y. Epub 2010 Dec 29.
Abstract
Original glycodendrimers emanating from propargylated hexaphenylbenzene cores and containing up to 54 peripheral sugar ligands have been synthesized by Cu(I)-catalyzed [1,3]-dipolar cycloadditions using both convergent and divergent approaches.
摘要
已通过使用汇聚和发散方法的铜 (I) 催化 [1,3]-偶极环加成反应合成了源自炔丙基化六苯基苯核并包含多达 54 个外围糖配体的原始糖树状大分子。
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