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聚[双-[μ-1-环丙基-6-氟-4-氧化-7-(1-哌嗪基)-1,4-二氢喹啉-3-羧酸根合]镍(II)]

Poly[bis-[μ-1-cyclo-propyl-6-fluoro-4-oxido-7-(1-piperazin-yl)-1,4-dihydro-quinoline-3-carboxyl-ato]nickel(II)].

作者信息

An Zhe, Liu Lan-Ru, Liu Ya-Qin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m176. doi: 10.1107/S1600536807065555.

DOI:10.1107/S1600536807065555
PMID:21200524
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915111/
Abstract

In the title compound, Ni(C(17)H(17)FN(3)O(3))(2), the Ni(II) atom exists in a distorted trans-NiN(2)O(4) octa-hedral geometry defined by two monodentate N-bonded and two bidentate O,O-bonded 1-cyclo-propyl-6-fluoro-4-oxido-7-(1-piperazin-yl)-1,4-dihydro-quinoline-3-carboxyl-ate (ciprofloxacinium) monoanions. The extended two-dimensional structure is a square grid. The Ni atom lies on a center of inversion.

摘要

在标题化合物[Ni(C₁₇H₁₇FN₃O₃)₂]ₙ中，Ni(II)原子处于扭曲的反式-NiN₂O₄八面体几何构型中，由两个单齿N键合和两个双齿O,O键合的1-环丙基-6-氟-4-氧化-7-(1-哌嗪基)-1,4-二氢喹啉-3-羧酸根（环丙沙星负离子）单阴离子所定义。扩展的二维结构是一个方格网。Ni原子位于一个对称中心上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbbf/2915111/ef98ad842422/e-64-0m176-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbbf/2915111/a0a048c0d53a/e-64-0m176-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbbf/2915111/ef98ad842422/e-64-0m176-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbbf/2915111/a0a048c0d53a/e-64-0m176-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbbf/2915111/ef98ad842422/e-64-0m176-fig2.jpg

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本文引用的文献

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Rationally designed, polymeric, extended metal-ciprofloxacin complexes.合理设计的聚合物型扩展金属-环丙沙星配合物。
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Pharmacokinetic interactions related to the chemical structures of fluoroquinolones.与氟喹诺酮类化学结构相关的药代动力学相互作用。
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