二乙腈-[N,N'-双-(3,4,5-三甲氧基-亚苄基)乙二胺]高氯酸铜(I)
Diacetonitrile-[N,N'-bis-(3,4,5-trimethoxy-benzyl-idene)ethyl-enediamine]copper(I) perchlorate.
作者信息
Khalaji Aliakbar Dehno, Brad Korbanjhon, Zhang Yan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m189. doi: 10.1107/S1600536807065919.
Abstract
In the title compound, [Cu(C(2)H(3)N)(2)(C(22)H(28)N(2)O(6))]ClO(4), the Cu atom is coordinated by two N atoms from one bidentate Schiff base ligand and two N atoms from two acetonitrile groups. The Cu atom adopts a tetra-hedral geometry. The Cu-N(ligand) distances are 2.076 (3) and 2.089 (3) Å, and the Cu-N(acetonitrile) distances are 1.964 (4) and 1.975 (4) Å.
摘要
在标题化合物[Cu(C₂H₃N)₂(C₂₂H₂₈N₂O₆)]ClO₄中，铜原子由一个双齿席夫碱配体的两个氮原子和两个乙腈基团的两个氮原子配位。铜原子采用四面体几何构型。Cu-N(配体)的距离为2.076 (3) Å和2.089 (3) Å，Cu-N(乙腈)的距离为1.964 (4) Å和1.975 (4) Å。
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