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二乙腈-[N,N'-双-(3,4,5-三甲氧基-亚苄基)乙二胺]高氯酸铜(I)

Diacetonitrile-[N,N'-bis-(3,4,5-trimethoxy-benzyl-idene)ethyl-enediamine]copper(I) perchlorate.

作者信息

Khalaji Aliakbar Dehno, Brad Korbanjhon, Zhang Yan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m189. doi: 10.1107/S1600536807065919.

DOI:10.1107/S1600536807065919
PMID:21200536
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915121/
Abstract

In the title compound, [Cu(C(2)H(3)N)(2)(C(22)H(28)N(2)O(6))]ClO(4), the Cu atom is coordinated by two N atoms from one bidentate Schiff base ligand and two N atoms from two acetonitrile groups. The Cu atom adopts a tetra-hedral geometry. The Cu-N(ligand) distances are 2.076 (3) and 2.089 (3) Å, and the Cu-N(acetonitrile) distances are 1.964 (4) and 1.975 (4) Å.

摘要

在标题化合物[Cu(C₂H₃N)₂(C₂₂H₂₈N₂O₆)]ClO₄中，铜原子由一个双齿席夫碱配体的两个氮原子和两个乙腈基团的两个氮原子配位。铜原子采用四面体几何构型。Cu-N(配体)的距离为2.076 (3) Å和2.089 (3) Å，Cu-N(乙腈)的距离为1.964 (4) Å和1.975 (4) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1e7/2915121/b8d8948e5b52/e-64-0m189-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1e7/2915121/b8d8948e5b52/e-64-0m189-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1e7/2915121/b8d8948e5b52/e-64-0m189-fig1.jpg

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