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链状聚[[[N,N'-双-(3-甲氧基-亚苄基)乙二胺]铜(I)]-μ-硫氰酸根合-κN:S]

catena-Poly[[[N,N'-bis-(3-methoxy-benzyl-idene)ethyl-enediamine]copper(I)]-μ-thio-cyanato-κN:S].

作者信息

Khalaji Aliakbar Dehno, Hadadzadeh Hassan, Gotoh Kazuma, Ishida Hiroyuki

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 13;65(Pt 1):m70. doi: 10.1107/S1600536808041925.

DOI:10.1107/S1600536808041925
PMID:21581537
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2967908/
Abstract

In the cyrstal structure of the title compound, Cu(NCS)(C(18)H(20)N(2)O(2)), the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

摘要

在标题化合物[Cu(NCS)(C₁₈H₂₀N₂O₂)]ₙ的晶体结构中，Cu(I)原子由一个双齿螯合席夫碱配体的两个亚氨基N原子以及两个硫氰酸根阴离子的一个N原子和一个S原子以扭曲的四面体几何构型配位。硫氰酸根阴离子桥连Cu(I)原子，沿[101]形成之字形链。席夫碱配体采用E,E构型，末端苯环之间的二面角为53.68 (8)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d67c/2967908/009394f1a890/e-65-00m70-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d67c/2967908/6c43152f3f60/e-65-00m70-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d67c/2967908/009394f1a890/e-65-00m70-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d67c/2967908/6c43152f3f60/e-65-00m70-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d67c/2967908/009394f1a890/e-65-00m70-fig2.jpg

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