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水合双(3,5-二甲基-1H-吡唑-κN)(草酸根-κO,O')铜(II)

Aqua-bis(3,5-dimethyl-1H-pyrazole-κN)(oxalato-κO,O')copper(II).

作者信息

Buvailo Andrii I, Tomyn Stefania V, Haukka Matti, Pavlenko Vadim A, Fritsky Igor O

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m37-8. doi: 10.1107/S1600536807058928.

Abstract

In the title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)(H(2)O)], the Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by two N atoms belonging to the two 3,5-dimethyl-1H-pyrazole ligands, two O atoms of the oxalate anion providing an O,O'-chelating coordination mode, and an O atom of the water mol-ecule occupying the apical position. The crystal packing shows a well defined layer structure. Intra-layer connections are realised through a system of hydrogen bonds while the nature of the inter-layer inter-actions is completely hydro-phobic, including no hydrogen-bonding inter-actions.

摘要

在标题化合物[Cu(C₂O₄)(C₅H₈N₂)₂(H₂O)]中,Cu(II)原子由两个属于两个3,5-二甲基-1H-吡唑配体的N原子、草酸根阴离子的两个O原子(提供O,O'-螯合配位模式)以及占据顶端位置的水分子的一个O原子以略微扭曲的四方锥几何构型配位。晶体堆积呈现出明确的层状结构。层内连接通过氢键体系实现,而层间相互作用的性质完全是疏水的,不包括氢键相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c18d/2914925/a443f300436e/e-64-00m37-fig1.jpg

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