Wang Suwen, Li Zhongfang, Wang Xutao, Yu Xianjin
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):m1232. doi: 10.1107/S1600536808021879.
The title compound, [Mn(C(2)H(5)O)(2)(C(44)H(28)N(4))]PF(6), was synthesized from manganese(III) 2,4-penta-nedionate and 5,10,15,20-tetra-phenyl-calix[4]pyrrole by a hydro-thermal reaction. The Mn(III) atom is located on an inversion centre and the asymmetric unit comprises one half-formula unit. The Mn(III) ion is hexa-coordinated by four N atoms from one 5,10,15,20-tetra-phenyl-calix[4]pyrrole ligand and two O atoms from two deprotonated ethanol mol-ecules. The equatorially located atoms (the Mn and four N atoms) are planar. The dihedral angles between the planes of the phenyl rings and the equatorial plane are 53.3 (2) and 81.8 (2)°. One hexa-fluoro-phosphate anion balances the charge.
标题化合物[Mn(C₂H₅O)₂(C₄₄H₂₈N₄)]PF₆是通过水热反应由2,4-戊二酮锰(III)和5,10,15,20-四苯基杯[4]吡咯合成的。Mn(III)原子位于一个对称中心上，不对称单元包含半个分子式单元。Mn(III)离子由来自一个5,10,15,20-四苯基杯[4]吡咯配体的四个N原子和来自两个去质子化乙醇分子的两个O原子六配位。位于赤道平面的原子（Mn和四个N原子）是平面的。苯环平面与赤道平面之间的二面角为53.3 (2)°和81.8 (2)°。一个六氟磷酸根阴离子平衡电荷。
