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聚[[(μ - 3,4 - 二羧基 - 四氢 - 呋喃 - 2,5 - 二羧基 - 合 - κO,O,O:O)(1,10 - 菲啰啉 - κN,N')铜(II)]] 0.69水合物

Poly[[(μ-3,4-dicarboxy-tetra-hydro-furan-2,5-dicarboxyl-ato-κO,O,O:O)(1,10-phenanthroline-κN,N')copper(II)] 0.69-hydrate].

作者信息

Lü Yuanqi

机构信息

Department of Chemistry, Dezhou University, University West Road 566, Dezhou, 253023, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):m1245. doi: 10.1107/S1600536808027918.

DOI:10.1107/S1600536808027918
PMID:21201002
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959334/
Abstract

In the crystal structure of the title compound, {[Cu(C(8)H(6)O(9))(C(12)H(8)N(2))]·0.69H(2)O}(n), the Cu(II) atom has a distorted octa-hedral geometry, coordinated by four O atoms from two 3,4-dicarboxy-tetra-hydro-furan-2,5-dicarboxyl-ate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the carboxylate groups bridges the Cu(II) atoms, forming a zigzag chain running along the b axis. The chains are linked by a π-π inter-action between aromatic rings with a centroid-to-centroid distance of 3.567 (1) Å, and by hydrogen bonds between the carboxyl-ate group and the disordered water mol-ecule, forming a three-dimensional network.

摘要

在标题化合物{[Cu(C₈H₆O₉)(C₁₂H₈N₂)]·0.69H₂O}ₙ的晶体结构中，Cu(II)原子具有扭曲的八面体几何构型，由来自两个3,4 - 二羧基 - 四氢 - 呋喃 - 2,5 - 二羧酸盐配体的四个O原子和来自一个1,10 - 菲咯啉配体的两个N原子配位。其中一个羧基桥连Cu(II)原子，形成沿b轴延伸的锯齿链。这些链通过芳香环之间的π - π相互作用（质心间距为3.567 (1) Å）以及羧酸盐基团与无序水分子之间的氢键相连，形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b38/2959334/96cfbbb883c3/e-64-m1245-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b38/2959334/030e00871b94/e-64-m1245-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b38/2959334/96cfbbb883c3/e-64-m1245-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b38/2959334/030e00871b94/e-64-m1245-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b38/2959334/96cfbbb883c3/e-64-m1245-fig2.jpg

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