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链状聚[[(吡啶-κN)铜(II)]-μ(3)-吡啶-2,6-二羧酸根-κO:O,N,O:O]

catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κO:O,N,O:O].

作者信息

Trivedi Manoj, Pandey Daya Shankar, Rath Nigam P

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):m303-4. doi: 10.1107/S1600536809005212.

Abstract

In the title compound, Cu(C(7)H(3)NO(4))(C(5)H(5)N), the Cu(II) atom is in a slightly distorted octa-hedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridine-dicarboxyl-ate (PDA) ligand in a tridentate manner, one N atom of the pyridine mol-ecule and two bridging carboxyl-ate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C-H⋯O and π-π inter-actions into a three-dimensional supra-molecular network structure. The centroid-centroid distance between the π-π inter-acting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu.

摘要

在标题化合物[Cu(C₇H₃NO₄)(C₅H₅N)]ₙ中,Cu(II)原子处于略微扭曲的八面体配位环境中。每个Cu(II)原子以三齿方式与吡啶 - 二羧酸酯(PDA)配体的两个N原子和一个O原子、吡啶分子的一个N原子以及相邻PDA配体的两个桥连羧酸酯O原子相连,形成沿c轴延伸的线性一维链。这些链通过弱C - H⋯O和π - π相互作用进一步组装成三维超分子网络结构。π - π相互作用的吡啶环之间的质心 - 质心距离为3.9104 (13) Å。两个N原子相对于Cu彼此呈反式。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/689e/2968654/6a65ff7c86aa/e-65-0m303-fig1.jpg

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