双（2-氨基-4-甲基-1,3-噻唑-κN）二氯化镉（II）
Bis(2-amino-4-methyl-1,3-thia-zole-κN)dichloridocadmium(II).
作者信息
Zhang Lai-Jun, Shen Xing-Can, Liang Hong
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):m1248. doi: 10.1107/S1600536808027864.
Abstract
In the title compound, [CdCl(2)(C(4)H(6)N(2)S)(2)], the Cd(II) atom is coordinated by two chlorido ligands and two N atoms of the 2-amino-5-methyl-1,3-thia-zole (amtz) ligands in a slightly distorted tetra-hedral coordination geometry. Intra- and inter-molecular N-H⋯Cl hydrogen bonding stabilizes the crystal structure. A weak S⋯Cl inter-action [3.533 (2) Å] is observed between neighboring mol-ecules.
摘要
在标题化合物[CdCl₂(C₄H₆N₂S)₂]中，Cd(II)原子由两个氯配体和2-氨基-5-甲基-1,3-噻唑（amtz）配体的两个N原子以略微扭曲的四面体配位几何构型配位。分子内和分子间的N-H⋯Cl氢键稳定了晶体结构。在相邻分子之间观察到一个弱的S⋯Cl相互作用[3.533 (2) Å]。
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