四（2-氨基噻唑-κN）二氯化镉（II）
Tetra-kis(2-amino-thia-zole-κN)dichloridocadmium(II).
作者信息
Kim Chong-Hyeak, Kim Inn Hoe
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):m13. doi: 10.1107/S1600536809051770.
Abstract
In the title complex, [CdCl(2)(C(3)H(4)N(2)S)(4)],the Cd(II) atom has an trans-Cl(2)N(4) octa-hedral coordination geometry defined by four N atoms derived from the four 2-amino-thia-zole ligands and two Cl atoms. The amino groups participate in intra- and inter-molecular N-H⋯N and N-H⋯Cl hydrogen bonding that stabilizes both the mol-ecular and crystal structures.
摘要
在标题配合物[CdCl₂(C₃H₄N₂S)₄]中，Cd(II)原子具有反式-Cl₂N₄八面体配位几何结构，由来自四个2-氨基噻唑配体的四个N原子和两个Cl原子确定。氨基参与分子内和分子间的N-H⋯N和N-H⋯Cl氢键作用，这使分子结构和晶体结构都得以稳定。
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