• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

反式-二水合双[5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧酸根合-κN,O]锰(II)

trans-Diaqua-bis[5-carb-oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl-ato-κN,O]manganese(II).

作者信息

Chen Li-Zhuang

机构信息

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 20;64(Pt 10):m1286. doi: 10.1107/S1600536808029073.

DOI:10.1107/S1600536808029073
PMID:21201031
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959396/
Abstract

In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydro-thermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octa-hedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water mol-ecules. A two-dimensional supra-molecular architecture is formed via N-H⋯O, O-H⋯N and O-H⋯O hydrogen-bonding inter-actions.

摘要

在通过水热反应合成的标题化合物[Mn(C₁₀H₆N₃O₄)₂(H₂O)₂]中，Mn(II)离子位于一个对称中心上，并呈现出一种扭曲的八面体配位几何构型，该构型由两个反式螯合配体的两个咪唑N原子、两个羧酸根O原子以及水分子的两个O原子所定义。通过N-H⋯O、O-H⋯N和O-H⋯O氢键相互作用形成了二维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db1b/2959396/6d9bdb0a2b27/e-64-m1286-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db1b/2959396/203b67eba8d6/e-64-m1286-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db1b/2959396/6d9bdb0a2b27/e-64-m1286-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db1b/2959396/203b67eba8d6/e-64-m1286-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db1b/2959396/6d9bdb0a2b27/e-64-m1286-fig2.jpg

相似文献

1
trans-Diaqua-bis[5-carb-oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl-ato-κN,O]manganese(II).反式-二水合双[5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧酸根合-κN,O]锰(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 20;64(Pt 10):m1286. doi: 10.1107/S1600536808029073.
2
trans-Diaqua-bis-[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-κN,O]cobalt(II).反式-二水合-双-[5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧酸根合-κN,O]钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1186. doi: 10.1107/S1600536811029618. Epub 2011 Aug 2.
3
Diaqua-bis-(5-carb-oxy-1H-imidazole-4-carboxyl-ato-κN,O)iron(II).二水合双（5-羧基-1H-咪唑-4-羧基根-κN，O）铁（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m997. doi: 10.1107/S1600536811024779. Epub 2011 Jun 30.
4
Diaqua-bis(5-carb-oxy-2-methyl-1H-imidazole-4-carboxyl-ato-κN,O)manganese(II).二水合双（5-羧基-2-甲基-1H-咪唑-4-羧酸根合-κN,O）锰（II）
Acta Crystallogr Sect E Struct Rep Online. 2008 Feb 15;64(Pt 3):m476. doi: 10.1107/S160053680800411X.
5
trans-Diaqua-bis-[4-carboxy-5-carboxyl-ato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κN,O]cobalt(II).反式-二水合-双-[4-羧基-5-羧基-2-(吡啶-1-鎓-4-基)-1H-咪唑-1-亚基-κN,O]钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1257. doi: 10.1107/S1600536811032545. Epub 2011 Aug 17.
6
Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O)manganese(II) N,N-dimethyl-formamide disolvate.二水合双（5-羧基-2-丙基-1H-咪唑-4-羧酸根-κN，O）锰（II）N，N-二甲基甲酰胺溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 24;66(Pt 1):m99. doi: 10.1107/S1600536809054634.
7
Diaqua-bis-(4-carb-oxy-2-ethyl-1H-imidazole-5-carboxyl-ato-κN,O)manganese(II) N,N-dimethyl-formamide disolvate.二水合双（4-羧基-2-乙基-1H-咪唑-5-羧基根合-κN,O）锰（II）N,N-二甲基甲酰胺溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m828. doi: 10.1107/S1600536811020071. Epub 2011 Jun 4.
8
Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-κN,O)copper(II) N,N-dimethyl-formamide disolvate.二水合双（4-羧基-2-丙基-1H-咪唑-5-羧基根-κN,O）铜（II）N,N-二甲基甲酰胺溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 7;66(Pt 8):m896. doi: 10.1107/S1600536810025249.
9
trans-Diaqua-bis[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-κN,O]iron(II).反式-二水合双[5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧酸根合-κN,O]铁(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m938-9. doi: 10.1107/S1600536809027457.
10
Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O)manganese(II) 3.5-hydrate.二水合双（5-羧基-2-丙基-1H-咪唑-4-羧基根合-κN，O）锰（II）3.5水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 18;66(Pt 9):m1096-7. doi: 10.1107/S1600536810031612.

引用本文的文献

1
Dimethyl-ammonium 5-carb-oxy-2-(1-oxo-1λ(5)-pyridin-2-yl)-1H-imidazole-4-car-box-yl-ate.5-羧基-2-(1-氧代-1λ(5)-吡啶-2-基)-1H-咪唑-4-羧酸二甲铵盐
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2600. doi: 10.1107/S1600536812033557. Epub 2012 Jul 28.
2
trans-Diaqua-bis-[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-κN,O]cobalt(II).反式-二水合-双-[5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧酸根合-κN,O]钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1186. doi: 10.1107/S1600536811029618. Epub 2011 Aug 2.
3
3-(4-Carb-oxy-5-carboxyl-ato-1H-imidazol-2-yl)pyridin-1-ium monohydrate.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Two stable 3D metal-organic frameworks constructed by nanoscale cages via sharing the single-layer walls.通过共享单层壁由纳米级笼子构建的两种稳定的三维金属有机框架。
J Am Chem Soc. 2006 Jan 11;128(1):34-5. doi: 10.1021/ja0567337.
3 -（4 - 羧基 - 5 - 羧基 - 1H - 咪唑 - 2 - 基）吡啶 - 1 - 鎓一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 26;67(Pt 2):o488. doi: 10.1107/S1600536811002248.