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六-μ(2)-乙酸根-κO:O'-μ(3)-氧代-三-[水合铬(III)]硝酸盐乙酸溶剂合物

Hexa-μ(2)-acetato-κO:O'-μ(3)-oxido-tris-[aqua-chromium(III)] nitrate acetic acid solvate.

作者信息

Maah Mohd Jamil, Abdullah Che Ibrahim, Gan Seng Neon, Mohd Jelan Aishah, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 24;64(Pt 10):m1310. doi: 10.1107/S1600536808029681.

Abstract

In the crystal structure of the title salt, [Cr(3)(C(2)H(3)O(2))(6)O(H(2)O)(3)]NO(3)·CH(3)CO(2)H, the trinuclear [Cr(3)(CH(3)CO(2))(6)O(H(2)O)(3)] cluster cation has an oxide O atom that is connected to three water-coordinated Cr(III) atoms, the three metal atoms forming the points of an equilateral triangle. Each of the six acetate carboxyl-ate groups bridges a Cr-O-Cr fragment. The cluster cation inter-acts with the nitrate counter-ion and solvent mol-ecules through O-H⋯O hydrogen bonds, forming a three-dimensional hydrogen-bonded network.

摘要

在标题盐[Cr₃(C₂H₃O₂)₆O(H₂O)₃]NO₃·CH₃CO₂H的晶体结构中,三核[Cr₃(CH₃CO₂)₆O(H₂O)₃]簇阳离子有一个氧化物O原子与三个水配位的Cr(III)原子相连,这三个金属原子构成一个等边三角形的顶点。六个乙酸根羧酸盐基团中的每一个都桥连一个Cr-O-Cr片段。簇阳离子通过O-H⋯O氢键与硝酸根抗衡离子和溶剂分子相互作用,形成三维氢键网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2924/2959480/eca2416ef74a/e-64-m1310-fig1.jpg

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