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聚[水合-[μ(3)-N'-(羧基甲基)乙二胺-N,N,N'-三乙酸根合]钐(III)]

Poly[aqua-[μ(3)-N'-(carboxy-meth-yl)ethyl-ene-diamine-N,N,N'-triacetato]samarium(III)].

作者信息

Zhou Guo-Yong, Wu Gui-Rong, Deng Zhi-Yong, Chen Xing-Tian

机构信息

Department of Chemistry and Biology Engineering, Hezhou University, Hezhou, Guangxi Zhuang Autonomous Region 542800, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 30;64(Pt 10):m1348. doi: 10.1107/S1600536808031036.

DOI:10.1107/S1600536808031036
PMID:21201077
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959472/
Abstract

In the title coordination polymer, Sm(C(10)H(13)N(2)O(8))(H(2)O), each samarium(III) centre is nine-coordinated by six O and two N atoms from three N'-(carboxy-meth-yl)ethyl-enediamine-N,N,N'-triacetate ligands and one O atom of a water mol-ecule, forming polymeric chains running parallel to the a axis. The packing is governed by inter-molecular O-H⋯O hydrogen-bonding inter-actions.

摘要

在标题配位聚合物[Sm(C₁₀H₁₃N₂O₈)(H₂O)]ₙ中，每个钐(III)中心由来自三个N'-(羧甲基)乙二胺-N,N,N'-三乙酸酯配体的六个O原子和两个N原子以及一个水分子的一个O原子九配位，形成平行于a轴的聚合物链。堆积由分子间O—H⋯O氢键相互作用控制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7434/2959472/36d0ee219e57/e-64-m1348-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7434/2959472/b19fb3a7b2a1/e-64-m1348-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7434/2959472/36d0ee219e57/e-64-m1348-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7434/2959472/b19fb3a7b2a1/e-64-m1348-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7434/2959472/36d0ee219e57/e-64-m1348-fig2.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 23;64(Pt 9):m1194. doi: 10.1107/S1600536808026445.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Hydrogen sorption in functionalized metal-organic frameworks.功能化金属有机框架中的氢吸附
J Am Chem Soc. 2004 May 12;126(18):5666-7. doi: 10.1021/ja049408c.
4
Synthesis and spectroscopic and structural studies of a new cadmium(II)-citrate aqueous complex. Potential relevance to cadmium(II)-citrate speciation and links to cadmium toxicity.一种新型镉（II）-柠檬酸盐水性配合物的合成、光谱及结构研究。与镉（II）-柠檬酸盐形态的潜在相关性以及与镉毒性的联系。
Inorg Chem. 2003 Apr 21;42(8):2531-7. doi: 10.1021/ic0205029.
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A pillared-layer coordination polymer network displaying hysteretic sorption: [Cu(2)(pzdc)(2)(dpyg)](n) (pzdc= pyrazine-2,3-dicarboxylate; dpyg=1,2-Di(4-pyridyl)glycol).
Angew Chem Int Ed Engl. 2002 Jan 4;41(1):133-5. doi: 10.1002/1521-3773(20020104)41:1<133::aid-anie133>3.0.co;2-r.