• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

二水合双[2-(2-吡啶甲氧基)吡嗪-κN]双(硫氰酸根-κN)钴(II)

Diaqua-bis[2-(2-pyridylmeth-oxy)pyrazine-κN]bis-(thio-cyanato-κN)cobalt(II).

作者信息

Yang Zhong Nian

机构信息

Department of Chemistry and Chemical Engineering, Binzhou University, Binzhou 256603, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 30;64(Pt 10):m1350. doi: 10.1107/S1600536808030882.

DOI:10.1107/S1600536808030882
PMID:21201079
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959305/
Abstract

In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, inter-molecular O-H⋯N and O-H⋯S hydrogen bonds link complex mol-ecules into a three-dimensional network.

摘要

在标题配合物[Co(NCS)₂(C₁₀H₉N₃O)₂(H₂O)₂]中,Co(II)离子位于一个晶体学二重旋转轴上,处于略微扭曲的八面体CoN₄O₂配位环境中。吡啶环和吡嗪环之间的二面角为85.86 (10)°。在晶体结构中,分子间的O—H⋯N和O—H⋯S氢键将配合物分子连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f1a/2959305/95359114b5c8/e-64-m1350-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f1a/2959305/d11b73bab23e/e-64-m1350-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f1a/2959305/95359114b5c8/e-64-m1350-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f1a/2959305/d11b73bab23e/e-64-m1350-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f1a/2959305/95359114b5c8/e-64-m1350-fig2.jpg

相似文献

1
Diaqua-bis[2-(2-pyridylmeth-oxy)pyrazine-κN]bis-(thio-cyanato-κN)cobalt(II).二水合双[2-(2-吡啶甲氧基)吡嗪-κN]双(硫氰酸根-κN)钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 30;64(Pt 10):m1350. doi: 10.1107/S1600536808030882.
2
Crystal structures of two Co(NCS) urotropine coordination compounds with different Co coordinations.两种具有不同钴配位方式的硫氰酸钴乌洛托品配位化合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2022 Feb 3;78(Pt 3):264-269. doi: 10.1107/S2056989022001037. eCollection 2022 Feb 1.
3
Crystal structures of tetra-kis-(pyridine-4-thio-amide-κ)bis-(thio-cyanato-κ)cobalt(II) monohydrate and bis-(pyridine-4-thio-amide-κ)bis-(thio-cyanato-κ)zinc(II).四 - (吡啶 - 4 - 硫代酰胺 - κ)双 - (硫氰酸根合 - κ)钴(II)一水合物和双 - (吡啶 - 4 - 硫代酰胺 - κ)双 - (硫氰酸根合 - κ)锌(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Jan 12;74(Pt 2):141-146. doi: 10.1107/S205698901800021X. eCollection 2018 Feb 1.
4
Bis(2-dimethylamino-1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)nickel(II) methanol disolvate.双(2-二甲基氨基-1,10-菲咯啉-κN,N')双(硫氰酸根合-κN)镍(II)甲醇溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 May 3;64(Pt 6):m769. doi: 10.1107/S1600536808011811.
5
Crystal structure of the tetra-aqua-bis-(thio-cyanato-κ)cobalt(II)-caffeine-water (1/2/4) co-crystal.四水合双(硫氰酸根-κ)钴(II)-咖啡因-水(1/2/4)共晶体的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Jun 7;73(Pt 7):980-982. doi: 10.1107/S2056989017008180. eCollection 2017 Jul 1.
6
catena-Poly[[diaqua-bis(thio-cyanato-κN)cobalt(II)]-μ-4,4'-bipyridine-κN:N'] 4,4'-bipyridine solvate].链状聚[[二水合双(硫氰酸根-κN)钴(II)]-μ-4,4'-联吡啶-κN:N']·4,4'-联吡啶溶剂化物]
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 24;65(Pt 7):m813. doi: 10.1107/S1600536809023265.
7
Crystal structure of di-aqua-bis-(2,6-di-methyl-pyrazine-κN)bis-(thio-cyanato-κN)cobalt(II) 2,5-di-methyl-pyrazine tris-olvate.二水双(2,6-二甲基吡嗪-κN)双(硫氰酸根-κN)钴(II)2,5-二甲基吡嗪三水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Dec 24;71(Pt 12):m269-70. doi: 10.1107/S2056989015024184. eCollection 2015 Dec 1.
8
Crystal structure of octa-kis-(4-meth-oxy-pyridinium) bis-(4-meth-oxy-pyridine-κ)tetra-kis-(thio-cyanato-κ)ferrate(III) bis-[(4-meth-oxypyri-dine-κ)pentakis-(thio-cyanato-κ)ferrate(III)] hexa-kis-(thio-cyanato-κ)ferrate(III) with iron in three different octa-hedral coordination environments.八 - 双(4 - 甲氧基吡啶鎓)双(4 - 甲氧基吡啶 - κ)四 - 双(硫氰酸根合 - κ)铁(III)双[(4 - 甲氧基吡啶 - κ)五 - 双(硫氰酸根合 - κ)铁(III)]六 - 双(硫氰酸根合 - κ)铁(III)的晶体结构,其中铁处于三种不同的八面体配位环境中。
Acta Crystallogr E Crystallogr Commun. 2018 Feb 2;74(Pt 3):287-291. doi: 10.1107/S2056989018001883. eCollection 2018 Mar 1.
9
Isolation and structural comparison of Ru-dnp complexes [dnp = 2,6-bis-(1,8-naphthyridin-2-yl)pyridine] with axially or equatorially coordinating NCS ligands.轴向或赤道配位的NCS配体的钌-二硝基吡啶配合物[二硝基吡啶=2,6-双-(1,8-萘啶-2-基)吡啶]的分离与结构比较。
Acta Crystallogr E Crystallogr Commun. 2022 May 6;78(Pt 6):545-549. doi: 10.1107/S2056989022004443. eCollection 2022 Jun 1.
10
Bis[N'-(2-pyridylmethyl-ene-κN)benzo-hydrazide-κN']bis-(thio-cyanato-κN)cobalt(II).双[N'-(2-吡啶基亚甲基-κN)苯甲酰肼-κN']双(硫氰酸根-κN)钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 25;65(Pt 8):m996. doi: 10.1107/S1600536809029006.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.