二水合双[2-(2-吡啶甲氧基)吡嗪-κN]双(硫氰酸根-κN)钴(II)
Diaqua-bis[2-(2-pyridylmeth-oxy)pyrazine-κN]bis-(thio-cyanato-κN)cobalt(II).
作者信息
Yang Zhong Nian
机构信息
Department of Chemistry and Chemical Engineering, Binzhou University, Binzhou 256603, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 30;64(Pt 10):m1350. doi: 10.1107/S1600536808030882.
In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, inter-molecular O-H⋯N and O-H⋯S hydrogen bonds link complex mol-ecules into a three-dimensional network.
在标题配合物[Co(NCS)₂(C₁₀H₉N₃O)₂(H₂O)₂]中，Co(II)离子位于一个晶体学二重旋转轴上，处于略微扭曲的八面体CoN₄O₂配位环境中。吡啶环和吡嗪环之间的二面角为85.86 (10)°。在晶体结构中，分子间的O—H⋯N和O—H⋯S氢键将配合物分子连接成三维网络。
Zotero 插件