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链状聚[[二水合双(硫氰酸根-κN)钴(II)]-μ-4,4'-联吡啶-κN:N']·4,4'-联吡啶溶剂化物]

catena-Poly[[diaqua-bis(thio-cyanato-κN)cobalt(II)]-μ-4,4'-bipyridine-κN:N'] 4,4'-bipyridine solvate].

作者信息

Yao Rufu, Wang Dong E

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 24;65(Pt 7):m813. doi: 10.1107/S1600536809023265.

Abstract

In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4'-bipyridine ligands, two O atoms from the water mol-ecule, and two N atoms from two isothio-cyanate ions in a distorted octa-hedral environment. In the crystal, the coordinated water mol-ecules, isothio-cyanate ions and solvent 4,4'-bipyridine mol-ecules are linked by O-H⋯S and O-H⋯N hydrogen bonds into layers parallel to the ab plane.

摘要

在标题配合物{[Co(NCS)₂(C₁₀H₈N₂)(H₂O)₂]·C₁₀H₈N₂}ₙ中,Co(II)离子位于一个对称中心上,在扭曲的八面体环境中,它由来自两个4,4'-联吡啶配体的两个N原子、来自水分子的两个O原子以及来自两个异硫氰酸根离子的两个N原子配位。在晶体中,配位水分子、异硫氰酸根离子和溶剂4,4'-联吡啶分子通过O—H⋯S和O—H⋯N氢键连接成平行于ab平面的层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aaef/2969491/f107b7de45c1/e-65-0m813-fig1.jpg

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