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N,N'-双(3-氯-2-氟-亚苄基)乙烷-1,2-二胺

N,N'-Bis(3-chloro-2-fluoro-benzyl-idene)ethane-1,2-diamine.

作者信息

Fun Hoong-Kun, Kia Reza

机构信息

X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):o1916. doi: 10.1107/S1600536808028419.

Abstract

The mol-ecule of the title centrosymmetric Schiff base compound, C(16)H(12)Cl(2)F(2)N(2), adopts an E configuration with respect to the azomethine C=N bond. The imino groups are coplanar with the aromatic rings. Within the mol-ecule, the planar units are parallel, but extend in opposite directions from the dimethyl-ene bridge. An inter-esting feature of the crystal structure is the short inter-molecular Cl⋯F [3.1747 (5) Å] inter-actions, which are shorter than the sum of the van der Waals radii of these atoms. These inter-actions link neighbouring mol-ecules along the b axis. The crystal structure is further stabilized by π-π inter-actions, with a centroid-centroid distance of 3.5244 (4) Å.

摘要

标题为中心对称席夫碱化合物C(16)H(12)Cl(2)F(2)N(2)的分子,相对于偶氮甲碱C=N键采用E构型。亚氨基与芳环共面。在分子内,平面单元相互平行,但从亚甲基桥向相反方向延伸。晶体结构的一个有趣特征是短的分子间Cl⋯F [3.1747 (5) Å]相互作用,其短于这些原子的范德华半径之和。这些相互作用沿b轴连接相邻分子。晶体结构通过π-π相互作用进一步稳定,质心-质心距离为3.5244 (4) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0537/2959267/0e046a429172/e-64-o1916-fig1.jpg

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