N,N'-双（3,5-二氯-亚苄基）-乙烷-1,2-二胺
N,N'-Bis(3,5-dichloro-benzyl-idene)-ethane-1,2-diamine.
作者信息
Fun Hoong-Kun, Kia Reza
机构信息
X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):o2131. doi: 10.1107/S1600536808033588.
Abstract
The mol-ecule of the title Schiff base compound, C(16)H(12)Cl(4)N(2), lies across an inversion centre and adopts an E configuration with respect to the azomethine C=N bond. The imine groups are coplanar with the aromatic rings. Within the mol-ecule, the planar units are parallel but extend in opposite directions from the dimethyl-ene bridge. In the crystal structure, mol-ecules are linked together by inter-molecular C-H⋯Cl hydrogen bonds along the a axis.
摘要
标题席夫碱化合物C(16)H(12)Cl(4)N(2)的分子位于一个对称中心上，相对于偶氮甲碱C=N键呈E构型。亚胺基团与芳环共面。在分子内，平面单元相互平行，但从亚甲基桥向相反方向延伸。在晶体结构中，分子沿a轴通过分子间C-H⋯Cl氢键连接在一起。
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