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双[甲基 2-(2-吡啶基亚甲基)肼基二硫代甲酸根合]锌(II)

Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II).

作者信息

Zhou Xiu-Xia, Zhou Zheng-Yuan, Chen Jian-Qiao, Lin Xiao-Ming, Cai Yue-Peng

机构信息

School of Chemistry and Environment, South China Normal University, Guangzhou 510631, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):m328-9. doi: 10.1107/S1600536807068493.

DOI:10.1107/S1600536807068493
PMID:21201296
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960303/
Abstract

In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure.

摘要

在标题化合物[Zn(C₈H₈N₃S₂)₂]中，锌原子通过吡啶基氮、偶氮甲碱氮和硫醇盐硫原子以三齿方式与两个配体配位；配位几何构型为扭曲八面体，两个配体呈反式构型（两个硫原子和两个吡啶基氮原子彼此顺式排列，偶氮甲碱氮原子反式排列）。分子通过C—H⋯S氢键相连，形成三维网络结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1050/2960303/e05fe2f1de9f/e-64-0m328-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1050/2960303/669592c27cd4/e-64-0m328-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1050/2960303/e05fe2f1de9f/e-64-0m328-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1050/2960303/669592c27cd4/e-64-0m328-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1050/2960303/e05fe2f1de9f/e-64-0m328-fig2.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
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2
Multidimensional frameworks assembled from silver(I) coordination polymers containing flexible bis(thioquinolyl) ligands: role of the intra- and intermolecular aromatic stacking interactions.由含柔性双（硫代喹啉基）配体的银（I）配位聚合物组装而成的多维框架：分子内和分子间芳香堆积相互作用的作用
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Synthesis, structural characterization and antimicrobial activities of 4- and 6-coordinate nickel(II) complexes with three thiosemicarbazones and semicarbazone ligands.
含三种硫代半卡巴腙和半卡巴腙配体的四配位和六配位镍（II）配合物的合成、结构表征及抗菌活性
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