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二氯-1κCl,3κCl-六-双[1,1,2,2,3,3(η)-甲基-环戊二烯基]二-μ(2)-氧化-1:2κO:O;2:3κO:O-三铪(IV)

Dichlorido-1κCl,3κCl-hexa-kis[1,1,2,2,3,3(η)-methyl-cyclo-penta-dienyl]di-μ(2)-oxido-1:2κO:O;2:3κO:O-trihafnium(IV).

作者信息

Wisniewska Aleksandra, Baranowska Katarzyna, Pikies Jerzy

机构信息

Department of Inorganic Chemistry, Faculty of Chemistry, Gdańsk University of Technology, 11/12 G. Narutowicz Street, 80952-PL Gdańsk, Poland.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 16;64(Pt 2):m361. doi: 10.1107/S1600536807061417.

DOI:10.1107/S1600536807061417
PMID:21201320
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960469/
Abstract

The title compound, [Hf(3)(C(6)H(7))(6)Cl(2)O(2)], is a trinuclear mol-ecule having two (MeCp)(2)HfCl units (MeCp is methyl-cyclo-penta-dien-yl) each connected to an (MeCp)(2)Hf unit by an oxide bridge. The two Hf-O-Hf bridges are nearly linear. The geometry of the three Hf atoms is tetra-hedral (assuming the MeCp group occupies one coordination site); the O-Hf-O angle is 99.8 (5)°. One of the Cl atoms is disordered, with site occupancies of 0.61 (7) and 0.39 (7).

摘要

标题化合物[Hf₃(C₆H₇)₆Cl₂O₂]是一种三核分子，具有两个(MeCp)₂HfCl单元（MeCp为甲基环戊二烯基），每个单元通过一个氧化物桥与一个(MeCp)₂Hf单元相连。两个Hf-O-Hf桥几乎呈线性。三个Hf原子的几何构型为四面体（假设MeCp基团占据一个配位位点）；O-Hf-O角为99.8 (5)°。其中一个Cl原子无序，占据率为0.61 (7)和0.39 (7)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47eb/2960469/912d4dac7e02/e-64-0m361-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47eb/2960469/912d4dac7e02/e-64-0m361-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47eb/2960469/912d4dac7e02/e-64-0m361-fig1.jpg

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引用本文的文献

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