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三氯-1κCl,2κCl-(2,6-二甲基苯酚根-2κO)-μ-氧代-双{1,2(η)-2,3,4,5-四甲基-1-[4-(三甲基硅基)苯基]环戊二烯基}二钛(IV)

Trichlorido-1κCl,2κCl-(2,6-dimethyl-phenolato-2κO)-μ-oxido-bis{1,2(η)-2,3,4,5-tetra-methyl-1-[4-(trimethyl-silyl)phen-yl]cyclo-penta-dien-yl}dititanium(IV).

作者信息

Luo Xuyang, Wu Qiaolin, Mu Ying

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1355. doi: 10.1107/S1600536811035306. Epub 2011 Sep 14.

DOI:10.1107/S1600536811035306
PMID:22064795
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201525/
Abstract

The title dinuclear titanocene, [Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O], contains one Ti atom tetra-hedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclo-penta-dienyl ligand, and another Ti atom tetra-hedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethyl-phenolate ligand and the substituted cyclo-penta-dienyl ligand. The bridging O atom lies on a twofold rotation axis.

摘要

双核钛茂配合物[Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O]的一个钛原子由两个氯原子、一个桥连氧原子和取代环戊二烯基配体呈四面体配位，另一个钛原子由一个氯原子、一个桥连氧原子、2,6-二甲基苯酚盐配体和取代环戊二烯基配体呈四面体配位。桥连氧原子位于一个二重旋转轴上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7276/3201525/307f0b1e9e5f/e-67-m1355-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7276/3201525/307f0b1e9e5f/e-67-m1355-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7276/3201525/307f0b1e9e5f/e-67-m1355-fig1.jpg

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