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二-μ-乙酸根合-κO:O'-双-{[2-(2-吡啶基)苯基-κC,N]钯(II)}

Di-μ-acetato-κO:O'-bis-{[2-(2-pyrid-yl)phenyl-κC,N]palladium(II)}.

作者信息

Dinçer Muharrem, Ozdemir Namık, Günay M Emin, Cetinkaya Bekir

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 23;64(Pt 2):m381. doi: 10.1107/S1600536808001736.

DOI:10.1107/S1600536808001736
PMID:21201336
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960165/
Abstract

In the title complex, [Pd(2)(C(11)H(8)N)(2)(C(2)H(3)O(2))(2)], each Pd(II) ion has a distorted square-planar environment, being surrounded by one C, one N and two O atoms. The Pd⋯Pd distance is 2.8721 (3) Å. In the crystal structure, the mol-ecules are linked by inter-molecular C-H⋯O inter-actions.

摘要

在标题配合物[Pd₂(C₁₁H₈N)₂(C₂H₃O₂)₂]中，每个Pd(II)离子具有扭曲的平面正方形环境，被一个C原子、一个N原子和两个O原子包围。Pd⋯Pd间距为2.8721(3) Å。在晶体结构中，分子通过分子间C—H⋯O相互作用相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb29/2960165/7dfa4e3704ee/e-64-0m381-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb29/2960165/d6ab28406144/e-64-0m381-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb29/2960165/7dfa4e3704ee/e-64-0m381-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb29/2960165/d6ab28406144/e-64-0m381-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb29/2960165/7dfa4e3704ee/e-64-0m381-fig2.jpg

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