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反式-二-μ-乙酸根-κO:O'-双-[2-(5-苯基异恶唑啉-3-基)苯基-κC,N]二钯(II)

trans-Di-μ-acetato-κO:O'-bis-[2-(5-phenyl-isoxazolin-3-yl)phenyl-κC,N]dipalladium(II).

作者信息

Zhou Jin, Wang Qibao, Sun Hongjian

机构信息

School of Chemistry and Chemical Engineering, Shandong University, Shanda Nanlu 27, Jinan 250100, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 May 17;64(Pt 6):m821. doi: 10.1107/S1600536808014141.

DOI:10.1107/S1600536808014141
PMID:21202504
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961565/
Abstract

The title compound, [Pd(2)(C(15)H(10)NO)(2)(C(2)H(3)O(2))(2)], crystallized from a dichloro-methane/n-hexane solution with two crystallographically independent dimeric mol-ecules in the asymmetric unit. Each mol-ecule may be described as a dimer with an anti configuration and the cyclo-metallated fragments in the characteristic open-book disposition, linked by two bridging acetate ligands.

摘要

标题化合物[Pd₂(C₁₅H₁₀NO)₂(C₂H₃O₂)₂]从二氯甲烷/正己烷溶液中结晶出来，不对称单元中有两个晶体学独立的二聚体分子。每个分子可描述为具有反式构型的二聚体，环金属化片段呈特征性的书页状排列，由两个桥连的乙酸根配体相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f95/2961565/40c4428ed314/e-64-0m821-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f95/2961565/40c4428ed314/e-64-0m821-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f95/2961565/40c4428ed314/e-64-0m821-fig1.jpg

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本文引用的文献

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Chem Rev. 2005 Jun;105(6):2527-71. doi: 10.1021/cr030681r.