一水合（对羟基苯甲酸根-κO）（对羟基苯甲酸根-κO,O'）（1,10-菲咯啉-κN,N'）锌（II）
Aqua(4-hydroxy-benzoato-κO)(4-hydroxy-benzoato-κO,O')(1,10-phenanthroline-κN,N')zinc(II) monohydrate.
作者信息
Kong Li-Li, Gao Shan, Huo Li-Hua, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m422. doi: 10.1107/S1600536808002249.
Abstract
The Zn atom in the title compound, [Zn(C(7)H(5)O(3))(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, exists in a distorted cis-ZnN(2)O(4) octa-hedral coordination geometry. One of the 4-hydroxy-benzoate anions chelates in a bidentate manner whereas the other is monodentate. The complex mol-ecules are linked through the uncoordinated water mol-ecules into a hydrogen-bonded sheet structure.
摘要
在标题化合物[Zn(C₇H₅O₃)₂(C₁₂H₈N₂)(H₂O)]·H₂O中，锌原子以扭曲的顺式-ZnN₂O₄八面体配位几何构型存在。4-羟基苯甲酸根阴离子中的一个以双齿方式螯合，而另一个为单齿。配合物分子通过未配位的水分子连接成氢键层状结构。
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