水合二氯双（1,10-菲咯啉-κN,N'）锌（II）氯化物N,N-二甲基甲酰胺溶剂化物
Aqua-chloridobis(1,10-phenanthroline-κN,N')zinc(II) chloride N,N-dimethyl-formamide solvate.
作者信息
Kong Li-Li, Gao Shan, Huo Li-Hua, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m423. doi: 10.1107/S1600536808002237.
The Zn atom in the title salt, [ZnCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·C(3)H(7)NO, is chelated by two phenanthroline mol-ecules and is bonded to one chloride ion and one water mol-ecule, resulting in a ZnN(4)ClO octa-hedral coordination environment with the Cl and O atoms in a cis conformation. The cations and anions are linked by O-H⋯Cl hydrogen bonds across a center of inversion, forming a hydrogen-bonded dimeric association. The dimethyl-formamide solvent mol-ecule is disordered over two orientations in a 0.56 (1):0.44 (1) ratio.
在标题盐[ZnCl(C₁₂H₈N₂)₂(H₂O)]Cl·C₃H₇NO中，锌原子被两个邻菲罗啉分子螯合，并与一个氯离子和一个水分子键合，形成一个ZnN₄ClO八面体配位环境，其中氯原子和氧原子呈顺式构象。阳离子和阴离子通过O—H⋯Cl氢键穿过一个反演中心相连，形成氢键二聚体缔合。二甲基甲酰胺溶剂分子在两个取向间无序排列，比例为0.56 (1):0.44 (1)。
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