Ravindran Durai Nayagam B, Jebas Samuel Robinson, Grace Selvarathi, Schollmeyer Dieter
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):o409. doi: 10.1107/S1600536807068766.
Mol-ecules of the title compound, C(22)H(24)N(2)O(2)S(2), lie across centres of inversion. The two thio-pyridine N-oxide groups adopt a stepped trans configuration with respect to the benzene ring, by virtue of the symmetry. The oxopyridinium ring forms a dihedral angle of 79.9 (2)° with the benzene ring. The crystal structure is stabilized by a strong π-π inter-action between the pyridinium rings of adjacent mol-ecules [ring centroid-centroid distance = 3.464 (3) Å].
标题化合物C(22)H(24)N(2)O(2)S(2)的分子位于反演中心上。由于对称性,两个硫代吡啶N-氧化物基团相对于苯环呈阶梯状反式构型。氧代吡啶鎓环与苯环形成的二面角为79.9 (2)°。晶体结构通过相邻分子的吡啶鎓环之间强烈的π-π相互作用得以稳定[环质心-质心距离 = 3.464 (3) Å]。