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聚[水合-[μ(2)-1,1'-(丁烷-1,4-二基)二咪唑](μ(2)-萘-1,4-二羧酸根合)镍(II)]

Poly[aqua-[μ(2)-1,1'-(butane-1,4-di-yl)diimidazole](μ(2)-naphthalene-1,4-dicarboxyl-ato)nickel(II)].

作者信息

Zou Xian-Zhi

机构信息

Department of Chemistry, College of Chemistry and Biology, Beihua University, Jilin City 132013, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):m1105. doi: 10.1107/S1600536808024008.

DOI:10.1107/S1600536808024008
PMID:21201571
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960619/
Abstract

In the title compound, Ni(C(12)H(6)O(4))(C(10)H(14)N(4))(H(2)O), the coordination polyhedron around each Ni(II) atom is a distorted cis-NiN(2)O(4) octa-hedron. The naphthalene-1,4-dicarboxyl-ate and 1,1'-(butane-1,4-di-yl)diimidazole ligands bridge the Ni centres to form a two-dimensional (4,4)-network, and O-H⋯O hydrogen bonds complete the structure.

摘要

在标题化合物[Ni(C₁₂H₆O₄)(C₁₀H₁₄N₄)(H₂O)]ₙ中，每个Ni(II)原子周围的配位多面体是一个扭曲的顺式-NiN₂O₄八面体。萘-1,4-二羧酸根和1,1'-（丁烷-1,4-二亚基）二咪唑配体连接Ni中心形成二维(4,4)网络，并且O—H⋯O氢键完善了该结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31b4/2960619/91beed4a50bc/e-64-m1105-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31b4/2960619/d9cd5b12d48d/e-64-m1105-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31b4/2960619/91beed4a50bc/e-64-m1105-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31b4/2960619/d9cd5b12d48d/e-64-m1105-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31b4/2960619/91beed4a50bc/e-64-m1105-fig2.jpg

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