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2
Di-μ-bromido-bis-[bromido(di-2-pyridylmethane-diol-κN,N')copper(II)] dihydrate.
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):m1122-3. doi: 10.1107/S1600536808024203.

本文引用的文献

1
Di-μ-bromido-bis-[bromido(di-2-pyridylmethane-diol-κN,N')copper(II)] dihydrate.
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):m1122-3. doi: 10.1107/S1600536808024203.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

链状聚[[μ-溴代-(μ-羟基二-2-吡啶甲烷醇根-κN,O:O,N')二铜(II)(铜-铜)]-二-μ-溴代]

catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano-lato-κN,O:O,N')dicopper(II)(Cu-Cu)]-di-μ-bromido].

作者信息

Zeller Matthias, Westcott Barry L, Kopp-Vaughn Kristin M, Hunter Allen D

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):m1121. doi: 10.1107/S1600536808024197.

DOI:10.1107/S1600536808024197
PMID:21201583
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960673/
Abstract

The title complex, Cu(2)Br(3)(C(11)H(9)N(2)O(2)), was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmethane-diol. The two copper centers are bridged by a bromide ion and the alk-oxy O atom, and the Cu-Cu distance is 2.9801 (5) Å. The dimeric units are further linked by bromide ions, leading to a two-dimensional extended bridged structure. O-H⋯O hydrogen bonds are present in the crystal structure.

摘要

标题配合物[Cu₂Br₃(C₁₁H₉N₂O₂)]ₙ是通过将CuBr₂与2,2'-联吡啶酮（摩尔比1:1）的乙腈反应混合物缓慢蒸发分离得到的三种配合物之一。标题配合物中铜(II)与配体水合形式2,2'-二吡啶甲烷二醇的金属与配体比例为2:1。两个铜中心由一个溴离子和烷氧基O原子桥联，Cu-Cu距离为2.9801(5) Å。二聚单元通过溴离子进一步连接，形成二维扩展桥联结构。晶体结构中存在O-H⋯O氢键。