双（2,6 - 二甲基吡啶鎓）六氯合铂（IV）
Bis(2,6-dimethyl-pyridinium) hexa-chlorido-platinate(IV).
作者信息
Amani Vahid, Rahimi Rahmatollah, Khavasi Hamid Reza
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 9;64(Pt 9):m1143-4. doi: 10.1107/S1600536808025257.
The asymmetric unit of the title compound, (C(7)H(10)N)(2)[PtCl(6)], contains one independent protonated 2,6-dimethyl-pyridinium cation and half of a centrosymmetric PtCl(6) anion. The Pt atom has an octa-hedral coordination. In the crystal structure, inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds result in the formation of a supra-molecular structure. There is a π-π contact between the pyridine rings [centroid-centroid distance = 4.235 (1) Å].
标题化合物(C₇H₁₀N)₂[PtCl₆]的不对称单元包含一个独立的质子化2,6-二甲基吡啶鎓阳离子和一个中心对称的[PtCl₆]²⁻阴离子的一半。Pt原子具有八面体配位。在晶体结构中，分子间的N-H⋯Cl和C-H⋯Cl氢键导致形成超分子结构。吡啶环之间存在π-π接触[质心-质心距离 = 4.235 (1) Å]。
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