双（菲啶鎓）六氯铂（IV）二甲亚砜溶剂化物
Bis(phenanthridinium) hexa-chloridoplatinate(IV) dimethyl sulfoxide disolvate.
作者信息
Karaca Selvi, Akkurt Mehmet, Safari Nasser, Amani Vahid, Büyükgüngör Orhan, Abedi Anita
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 28;65(Pt 2):m235. doi: 10.1107/S1600536809002736.
Abstract
The asymmetric unit of the title compound, (C(13)H(10)N)(2)[PtCl(6)]·2C(2)H(6)OS, contains one independent protonated phenanthridinium cation, half of a centrosymmetric PtCl(6)anion and one dimethyl sulfoxide solvent mol-ecule. Intra-molecular N-H⋯O and inter-molecular C-H⋯Cl hydrogen-bonding inter-actions seem to be effective in the stabilization of the structure.
摘要
标题化合物（C₁₃H₁₀N）₂[PtCl₆]·2C₂H₆OS的不对称单元包含一个独立的质子化菲啶鎓阳离子、一个中心对称的[PtCl₆]²⁻阴离子的一半以及一个二甲基亚砜溶剂分子。分子内N—H⋯O和分子间C—H⋯Cl氢键相互作用似乎对结构的稳定有效。
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