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链状聚[[(2-{1-[2-(2-氨基-乙基-氨基)乙基-亚氨基]-乙基}-5-甲氧基-苯酚根合-κN,N',N'',O)铜(II)]-μ-硝酸根合-κO:O']

catena-Poly[[(2-{1-[2-(2-amino-ethyl-amino)ethyl-imino]-eth-yl}-5-methoxy-phenolato-κN,N',N'',O)copper(II)]-μ-nitrato-κO:O'].

作者信息

Wang Suwen, Li Zhongfang, Wang Xutao, Yu Xianjin

机构信息

College of Chemical Engineering, Shandong University of Technology, Zibo 255049, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 23;64(Pt 9):m1193. doi: 10.1107/S1600536808021880.

DOI:10.1107/S1600536808021880
PMID:21201632
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960731/
Abstract

In the title compound, Cu(C(13)H(20)N(3)O(2))(NO(3)), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol-ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu-O bonds of 2.535 (6) and 2.676 (7) Å, completing a distorted octa-hedral coordination geometry. The NH groups of the ligand form hydrogen bonds to the nitrate anions.

摘要

在标题化合物[Cu(C₁₃H₂₀N₃O₂)(NO₃)]ₙ中，Cu(II)原子通过位于近似正方形平面内的三个N原子和一个O原子被席夫碱配体螯合（均方根偏差 = 0.04 Å）。配合物分子通过桥连硝酸根阴离子连接成聚合物链，形成了2.535 (6) Å和2.676 (7) Å的轴向Cu - O键，构成了扭曲的八面体配位几何结构。配体的NH基团与硝酸根阴离子形成氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f491/2960731/1ea8ff6091b5/e-64-m1193-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f491/2960731/1ea8ff6091b5/e-64-m1193-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f491/2960731/1ea8ff6091b5/e-64-m1193-fig1.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.