（乙酰丙酮根-κO,O'）（2-溴-4-氯-6-{[2-（二甲基氨基）-乙基亚氨基]-甲基}苯酚根-κN,N',O）氧钒（IV）
(Acetyl-acetonato-κO,O')(2-bromo-4-chloro-6-{[2-(dimethyl-amino)-ethyl-imino]-meth-yl}phenolato-κN,N',O)oxidovanadium(IV).
作者信息
Wang Fu-Ming
机构信息
Department of Chemistry, Dezhou University, Dezhou Shandong 253023, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m650. doi: 10.1107/S1600536811015406. Epub 2011 Apr 29.
The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetyl-acetonate anion, forming a distorted cis-VN(2)O(4) octa-hedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetyl-acetone ligand towards the oxide O atom is 0.256 (2) Å.
在标题配合物[V(C₁₁H₁₃BrClN₂O)(C₅H₇O₂)O]中，V(IV)原子由三齿阴离子席夫碱配体的一个酚氧原子、一个亚氨基氮原子和一个氨基氮原子、一个氧化物氧原子以及乙酰丙酮阴离子的两个氧原子进行六配位，形成扭曲的顺式-VN₂O₄八面体配位几何构型。V原子偏离由席夫碱配体的三个供体原子和乙酰丙酮配体的一个氧原子所定义平面并朝向氧化物氧原子的距离为0.256 (2) Å。
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