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高氯酸（2-{[2-(2-氨基-乙基-氨基)-乙基-亚氨基]-甲基}苯酚根-κO,N',N'',N''')铜(II)

(2-{[2-(2-Amino-ethyl-amino)-ethyl-imino]-meth-yl}phenolato-κO,N',N'',N''')copper(II) perchlorate.

作者信息

Dieng Moussa, Barry Aliou Hamady, Gaye Mohamed, Sall Abdou Salam, Pérez-Lourido Paulo, Valencia-Matarranz Laura

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m830-1. doi: 10.1107/S1600536811020095. Epub 2011 Jun 4.

DOI:10.1107/S1600536811020095
PMID:21836840
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3152086/
Abstract

The asymmetric unit of the title complex, [Cu(C(11)H(16)N(3)O)]ClO(4), consists of two Cu(II) ions coordinated by Schiff base ligands and two perchlorate anions. The Schiff base mol-ecules are linked to the Cu(II) atoms via three N atoms and one O atom, resulting in a square-planar geometry. Inter-molecular hydrogen bonds involving the NH groups as donors and O atoms of the perchlorate anions as acceptors are observed.

摘要

标题配合物[Cu(C₁₁H₁₆N₃O)]ClO₄的不对称单元由两个由席夫碱配体配位的Cu(II)离子和两个高氯酸根阴离子组成。席夫碱分子通过三个N原子和一个O原子与Cu(II)原子相连，形成平面正方形几何结构。观察到分子间氢键，其中NH基团作为供体，高氯酸根阴离子的O原子作为受体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4788/3152086/870f36e100df/e-67-0m830-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4788/3152086/d4794b91152b/e-67-0m830-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4788/3152086/870f36e100df/e-67-0m830-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4788/3152086/d4794b91152b/e-67-0m830-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4788/3152086/870f36e100df/e-67-0m830-fig2.jpg

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本文引用的文献

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