Choi Hong Dae, Seo Pil Ja, Son Byeng Wha, Lee Uk
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1711. doi: 10.1107/S1600536808024689.
The title compound, C(13)H(14)O(4)S, was prepared by oxidation of methyl 2-(5-methyl-3-methyl-sulfanyl-1-benzofuran-2-yl)acetate with 3-chloro-peroxy-benzoic acid. The O atom and methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The crystal structure is stabilized by inter-molecular aromatic π-π inter-actions between the benzene rings of neighbouring mol-ecules, with a centroid-centroid separation of 3.841 (3) Å.
标题化合物C₁₃H₁₄O₄S是通过用3-氯过氧苯甲酸氧化2-(5-甲基-3-甲基硫烷基-1-苯并呋喃-2-基)乙酸甲酯制备的。甲基亚磺酰取代基的O原子和甲基位于苯并呋喃体系平面的两侧。晶体结构通过相邻分子苯环之间的分子间芳香π-π相互作用得以稳定,质心间距为3.841(3) Å。