2-（5-甲基-3-甲基亚磺酰基-1-苯并呋喃-2-基）乙酸异丙酯
Isopropyl 2-(5-methyl-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.
作者信息
Choi Hong Dae, Seo Pil Ja, Son Byeng Wha, Lee Uk
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 9;64(Pt 11):o2079. doi: 10.1107/S1600536808031796.
Abstract
The title compound, C(15)H(18)O(4)S, was prepared by the oxidation of isopropyl 2-(5-methyl-3-methyl-sulfanyl-1-benzofuran-2-yl)acetate with 3-chloro-peroxy-benzoic acid. The crystal structure is stabilized by inter-molecular π-π inter-actions between the benzene rings; the centroid-centroid distance between the adjacent benzene rings (symmetry code: ) is 3.713 (2) Å. In addition, C-H⋯π and weak inter-molecular C-H⋯O inter-actions are present in the structure.
摘要
标题化合物C(15)H(18)O(4)S是通过用3-氯过氧苯甲酸氧化异丙基2-(5-甲基-3-甲基硫烷基-1-苯并呋喃-2-基)乙酸酯制备的。晶体结构通过苯环之间的分子间π-π相互作用得以稳定；相邻苯环之间的质心-质心距离（对称代码： ）为3.713 (2) Å。此外，结构中还存在C-H⋯π和弱分子间C-H⋯O相互作用。
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