Gao Bo
Marine College, Zhejiang Institute of Communications, Hangzhou 311112, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 16;64(Pt 9):o1766. doi: 10.1107/S1600536808025191.
In the mol-ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl-ate mean plane is 3.65 (12)°. Intra-molecular C-H⋯N and O-H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, inter-molecular N-H⋯O and C-H⋯N hydrogen bonds link the mol-ecules. There is a C-H⋯π contact between the benzene ring and the methyl group of the ethyl substituent.
在标题化合物C(11)H(14)N(2)O(3)的分子中,苯环与肼羧酸酯平均平面之间的二面角为3.65 (12)°。分子内的C-H⋯N和O-H⋯N氢键导致形成一个近乎平面的六元环,该六元环相对于苯环的二面角为2.38 (3)°,还有一个具有信封构象的五元环。在晶体结构中,分子间的N-H⋯O和C-H⋯N氢键将分子连接起来。苯环与乙基取代基的甲基之间存在C-H⋯π接触。