• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（E）-N'-[1-（4-甲氧基苯基）亚乙基]肼羧酸乙酯

(E)-Ethyl N'-[1-(4-methoxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

作者信息

Lv Lu-Ping, Xie Jian-Wu, Yu Wen-Bo, Mao Yu-Hui, Hu Xian-Chao

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 4;64(Pt 11):o2062. doi: 10.1107/S1600536808031462.

DOI:10.1107/S1600536808031462
PMID:21580928
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959676/
Abstract

The mol-ecule of the title compound, C(12)H(16)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 13.82 (6)°. In the crystal structure, mol-ecules are linked into centrosymmetric dimers by N-H⋯O and C-H⋯O hydrogen bonds, and the dimers are linked together by C-H⋯π inter-actions.

摘要

标题化合物C(12)H(16)N(2)O(3)的分子相对于C=N键采取反式构型。苯环与肼羧酸酯平面之间的二面角为13.82 (6)°。在晶体结构中，分子通过N-H⋯O和C-H⋯O氢键连接成中心对称的二聚体，并且二聚体通过C-H⋯π相互作用连接在一起。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f941/2959676/8abb152cfa76/e-64-o2062-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f941/2959676/d79370e04d0f/e-64-o2062-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f941/2959676/8abb152cfa76/e-64-o2062-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f941/2959676/d79370e04d0f/e-64-o2062-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f941/2959676/8abb152cfa76/e-64-o2062-fig2.jpg

相似文献

1
(E)-Ethyl N'-[1-(4-methoxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（4-甲氧基苯基）亚乙基]肼羧酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 4;64(Pt 11):o2062. doi: 10.1107/S1600536808031462.
2
(E)-Methyl N'-[1-(4-methyl-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（4-甲基苯基）亚乙基]肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 4;64(Pt 11):o2071. doi: 10.1107/S160053680803184X.
3
(E)-Methyl N'-[1-(4-methoxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（4-甲氧基苯基）亚乙基]肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1676. doi: 10.1107/S1600536808024264.
4
(E)-Methyl N'-[1-(2-hydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（2-羟基苯基）亚乙基]肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 13;64(Pt 9):o1748. doi: 10.1107/S1600536808024434.
5
Methyl (E)-N'-[1-(2,4-dihydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（2,4-二羟基苯基）亚乙基]肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):o1896. doi: 10.1107/S1600536809027317.
6
(E)-Methyl N'-[1-(4-hydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（4-羟基苯基）亚乙基]肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1675. doi: 10.1107/S1600536808024227.
7
Ethyl N'-[(E)-4-hydroxy-benzyl-idene]hydrazinecarboxyl-ate at 123 K.N'-[(E)-4-羟基-亚苄基]肼基甲酸乙酯，温度为123 K。
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):o1396. doi: 10.1107/S1600536808019818.
8
(E)-Ethyl N'-[1-(2-hydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（2-羟基苯基）亚乙基]肼基甲酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 16;64(Pt 9):o1766. doi: 10.1107/S1600536808025191.
9
(E)-Ethyl N'-(3,4,5-trimethoxy-benzyl-idene)hydrazinecarboxyl-ate.（E）-N'-（3,4,5-三甲氧基-亚苄基）肼基甲酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):o2127. doi: 10.1107/S1600536808033461.
10
Methyl N'-[(E)-1-phenyl-ethyl-idene]hydrazinecarboxyl-ate.N'-[(E)-1-苯基-亚乙基]肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):o1384. doi: 10.1107/S1600536808019259.

本文引用的文献

1
(E)-Methyl N'-[1-(4-methoxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.（E）-N'-[1-（4-甲氧基苯基）亚乙基]肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1676. doi: 10.1107/S1600536808024264.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Design, synthesis, and evaluation of Phe-Gly mimetics: heterocyclic building blocks for pseudopeptides.
J Med Chem. 1999 Oct 21;42(21):4331-42. doi: 10.1021/jm990197+.