6 - （2 - 氯苄基氨基）嘌呤四氯化（二甲亚砜 - κO）（亚硝酰 - κN）钌（III）一水合物
6-(2-Chloro-benzyl-amino)purinium tetra-chlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate.
作者信息
Trávníček Zdeněk, Matiková-Maľarová Miroslava, Stěpánková Kamila
机构信息
Department of Inorganic Chemistry, Faculty of Science, Palacký University, Křížkovského 10, CZ-771 47 Olomouc, Czech Republic.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 14;64(Pt 4):m545-6. doi: 10.1107/S1600536808006673.
The asymmetric unit of the title complex salt, (C(12)H(11)ClN(5))[RuCl(4)(NO)(C(2)H(6)OS)]·H(2)O, contains a 6-(2-chloro-benzyl-amino)purinium cation, a tetra-chlorido(dimethyl sulfoxide)nitro-sylruthenate(III) anion and one solvent water mol-ecule. The Ru(III) atom is octa-hedrally coordinated by four Cl atoms in the equatorial plane, and by a dimethyl sulfoxide O atom and a nitrosyl N atom in axial positions. The cation is an N3-protonated N7 tautomer. Inter-molecular N-H⋯N hydrogen bonds connect two cations into centrosymmetric dimers, with an N⋯N distance of 2.821 (4) Å. The crystal structure also involves N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds.
标题配合物盐（C₁₂H₁₁ClN₅）[RuCl₄(NO)(C₂H₆OS)]·H₂O的不对称单元包含一个6-(2-氯苄基氨基)嘌呤阳离子、一个四氯（二甲亚砜）亚硝酰钌(III)阴离子和一个溶剂水分子。Ru(III)原子在赤道平面上由四个Cl原子八面体配位，在轴向位置由一个二甲亚砜O原子和一个亚硝酰N原子配位。阳离子是N3质子化的N7互变异构体。分子间N-H⋯N氢键将两个阳离子连接成中心对称二聚体，N⋯N距离为2.821 (4) Å。晶体结构还涉及N-H⋯O、N-H⋯Cl和O-H⋯Cl氢键。
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