三氯（4,4'-二甲基-2,2'-联吡啶-κN,N'）（二甲亚砜-κO）铟（III）
Trichlorido(4,4'-dimethyl-2,2'-bipyridine-κN,N')(dimethyl sulfoxide-κO)indium(III).
作者信息
Ahmadi Roya, Kalateh Khadijeh, Abedi Anita, Amani Vahid, Khavasi Hamid Reza
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 20;64(Pt 10):m1306-7. doi: 10.1107/S1600536808029553.
Abstract
In the mol-ecule of the title compound, [InCl(3)(C(12)H(12)N(2))(C(2)H(6)OS)], the In(III) atom is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from dimethyl sulfoxide and three Cl atoms. In the crystal structure, inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers.
摘要
在标题化合物[InCl₃(C₁₂H₁₂N₂)(C₂H₆OS)]的分子中，In(III)原子由螯合的4,4'-二甲基-2,2'-联吡啶配体的两个N原子、二甲亚砜的一个O原子和三个Cl原子以扭曲的八面体构型进行六配位。在晶体结构中，分子间的C—H⋯Cl氢键将分子连接成中心对称的二聚体。
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