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水合氯代二甲基苯基锡(IV)-15-冠-5(2/1)

Aqua-chloridodimethyl-phenyltin(IV)-15-crown-5 (2/1).

作者信息

Armaghan Mahsa, Amini Mostafa M, Azadmehr Amirreza, Gao Shan, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 26;64(Pt 5):m721. doi: 10.1107/S1600536808011070.

Abstract

The Sn(IV) atom in the title compound, 2[Sn(CH(3))(2)(C(6)H(5))Cl(H(2)O)]·C(10)H(20)O(5), exists in a trans-C(3)SnClO trigonal bipyramidal geometry in which the organo substituents occupy the equatorial sites. The coordinated water mol-ecule forms two hydrogen bonds to the 15-crown-5 mol-ecule, which is disordered about a center of inversion.

摘要

标题化合物2[Sn(CH₃)₂(C₆H₅)Cl(H₂O)]·C₁₀H₂₀O₅中的Sn(IV)原子呈反式-C₃SnClO三角双锥几何构型,其中有机取代基占据赤道平面位置。配位水分子与15-冠-5分子形成两个氢键,15-冠-5分子关于一个反演中心无序。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8c3/2961118/5559ac77980c/e-64-0m721-fig1.jpg

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本文引用的文献

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Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

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