环戊基二苯基（4-硫代氨基脲基戊酸根-κO）锡（IV）
Cyclo-pentyl-diphen-yl(4-thio-semi-carbazonopenta-noato-κO)tin(IV).
作者信息
Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 26;64(Pt 5):m722-3. doi: 10.1107/S1600536808011112.
The Sn atom in the title compound, [Sn(C(5)H(9))(C(6)H(5))(2)(C(6)H(10)N(3)O(2)S)], exists within a tetra-hedral geometry. The -NH(2) group forms a weak hydrogen bond across a center of inversion to the S atom of an adjacent mol-ecule, as well as another weaker hydrogen (across another center of inversion) to the Sn-bound O atom of another mol-ecule. The hydrogen-bonded layer structure is consolidated by a strong hydrogen bond between the -NH- group and the uncoordinated O atom of a third mol-ecule.
在标题化合物[Sn(C₅H₉)(C₆H₅)₂(C₆H₁₀N₃O₂S)]中，Sn原子呈四面体几何构型。-NH₂基团通过一个反演中心与相邻分子的S原子形成弱氢键，同时还通过另一个反演中心与另一个分子中与Sn相连的O原子形成另一个较弱的氢键。氢键层结构通过-NH-基团与第三个分子的未配位O原子之间的强氢键得以巩固。
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