（丙酮-κO）{6,6'-二叔丁基-2,2'-[1,2-亚苯基双（亚氨基次甲基）]二酚根合-κO，N，N'，O'}锌（II）
(Acetone-κO){6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}zinc(II).
作者信息
Eltayeb Naser Eltaher, Teoh Siang Guan, Chantrapromma Suchada, Fun Hoong-Kun, Adnan Rohana
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 30;64(Pt 5):m738-9. doi: 10.1107/S1600536808011215.
The mol-ecule of the title compound, [Zn(C(28)H(30)N(2)O(2))(CH(3)COCH(3))], lies across a mirror plane with the Zn(II) ion and the acetone mol-ecule on the mirror plane. The Zn(II) ion is in a five-coordinate distorted square-pyramidal N(2)O(3) environment, with the two imine N and two phenolic O atoms of the tetra-dentate Schiff base dianion in the basal plane and the acetone mol-ecule in the apical position. The central benzene ring makes a dihedral angle of 16.5 (2)° with the two outer phenolate rings. In the crystal structure, the mol-ecules are arranged into anti-parallel columns along the a axis.
标题化合物[Zn(C₂₈H₃₀N₂O₂)(CH₃COCH₃)]的分子位于一个镜面平面上，锌(II)离子和丙酮分子位于该镜面平面上。锌(II)离子处于五配位扭曲的四方锥N₂O₃环境中，四齿席夫碱二价阴离子的两个亚胺氮原子和两个酚氧原子位于基面，丙酮分子位于顶端位置。中心苯环与两个外侧酚盐环形成的二面角为16.5 (2)°。在晶体结构中，分子沿a轴排列成反平行柱。
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