Peng Sanjun, Zhang Fen
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m799. doi: 10.1107/S1600536809022326.
The title mononuclear zinc(II) complex, [Zn(C(11)H(16)N(2)O(2))(2)(NCS)]NCS·0.5H(2)O, consists of a complex cation, a thio-cyanate anion, and half of a water mol-ecule. The Zn(II) atom in the cation is five-coordinated by two imine N and two phenolate O atoms from two bidentate Schiff base ligands, and by one N atom of a thio-cyanate ligand, forming a distorted trigonal-bipyramidal geometry. The ammonio H atoms are involved in hydrogen bonding with the ligand O atoms and the solvent water molecules (site occupation factor 0.5), which partially determines the conformation of the ligands.
标题单核锌（II）配合物[Zn(C₁₁H₁₆N₂O₂)₂(NCS)]NCS·0.5H₂O由一个配合物阳离子、一个硫氰酸根阴离子和半个水分子组成。阳离子中的Zn（II）原子由来自两个双齿席夫碱配体的两个亚胺N原子和两个酚氧O原子以及硫氰酸根配体的一个N原子五配位，形成扭曲的三角双锥几何构型。铵基H原子参与与配体O原子和溶剂水分子的氢键作用（占位因子0.5），这部分决定了配体的构象。
