Abedi Anita, Mousavi Mirkolaei Maryam, Amani Vahid
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 7;64(Pt 7):m888-9. doi: 10.1107/S1600536808015316.
In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxyl-ate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four ligands and two water mol-ecules. The coordination polyhedron is derived from a penta-gonal bipyramid with an O atom at the apex on one side of the equatorial plane and two O atoms sharing the apical site on the other side. The coordinated and uncoordinated water mol-ecules are involved in O-H⋯O and O-H⋯N hydrogen bonds, which consolidate the crystal structure.
在标题化合物{[Sr(C₆H₂N₂O₄)(H₂O)₂]·H₂O}ₙ中,Sr(II)离子由吡嗪 - 2,3 - 二羧酸根配体桥连,形成平行于ac平面的二维聚合物层。每个Sr(II)离子由来自四个配体的一个N原子、五个O原子和两个水分子八配位。配位多面体源自一个五角双锥,赤道平面一侧的顶点为一个O原子,另一侧的顶点由两个O原子共享。配位和未配位的水分子参与O - H⋯O和O - H⋯N氢键,巩固了晶体结构。