Xia Qiao-Hua, Guo Zhong-Fu, Liu Li, Wang Zhi-Kun, Li Bing
College of Sciences, Zhejiang A&F University, Lin'an, Hangzhou, Zhejiang 311300, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1395. doi: 10.1107/S1600536812043206. Epub 2012 Oct 20.
In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxyl-ate ligands, and two water mol-ecules. The water mol-ecules occupy basal and apical positions of the square-pyramidal coordination polyhedron. Each quinoline-2,3-dicarboxyl-ate dianion bridges two adjacent Cu(II) ions, forming a polymeric chain along [010]. The chains are further connected via O-H⋯O hydrogen-bonding inter-actions and quinoline ring π-π inter-actions [centroid-centroid distance = 3.725 (4) Å], generating a three-dimensional structure. Lattice water mol-ecules participate in the crystal structure via O-H⋯O hydrogen bonds.
在标题化合物{[Cu(C₁₁H₅NO₄)(H₂O)₂]·H₂O}ₙ中,Cu(II)离子由两个对称相关的喹啉 - 2,3 - 二羧酸酯配体的两个O原子、一个N原子以及两个水分子进行五配位。水分子占据四方锥配位多面体的基底和顶端位置。每个喹啉 - 2,3 - 二羧酸根二价阴离子桥连两个相邻的Cu(II)离子,沿[010]方向形成一条聚合链。这些链通过O—H⋯O氢键相互作用和喹啉环π - π相互作用[质心 - 质心距离 = 3.725 (4) Å]进一步连接,形成三维结构。晶格水分子通过O—H⋯O氢键参与晶体结构。