Riddell Nicole, McCrindle Robert, Arsenault Gilles, Lough Alan J
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 13;64(Pt 7):o1250. doi: 10.1107/S160053680801622X.
The title compound, C(18)H(13)Cl(11), is an undecachlorinated commercial flame retardant. The asymmetric unit contains two independent half-mol-ecules. The complete mol-ecules are generated by crystallographic inversion symmetry, causing the terminal H atoms and one of the Cl atoms to be disordered equally over two sites in each mol-ecule. The central eight-membered rings are in chair-type conformations. In the crystal structure, there is a single weak inter-molecular C-H⋯Cl hydrogen bond.
标题化合物C(18)H(13)Cl(11)是一种十一氯代商业阻燃剂。不对称单元包含两个独立的半分子。完整的分子由晶体学反演对称性产生,导致每个分子中的末端H原子和一个Cl原子在两个位置上均等无序。中心的八元环呈椅式构象。在晶体结构中,存在一个单一的弱分子间C-H⋯Cl氢键。