• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

4-[(E)-(3-氯-4-甲基苯基)亚氨基甲基]-2-甲氧基-3-硝基苯基乙酸酯

4-[(E)-(3-Chloro-4-methyl-phen-yl)imino-meth-yl]-2-methoxy-3-nitro-phenyl acetate.

作者信息

Su Deng-Cheng, Wang Feng-Ting, Mao Cheng-Gong, Qian Shao-Song

机构信息

School of Life Sciences, Shandong University of Technology, ZiBo 255049, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o303. doi: 10.1107/S1600536811055590. Epub 2012 Jan 7.

DOI:10.1107/S1600536811055590
PMID:22346941
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3274996/
Abstract

The title compound, C(17)H(15)ClN(2)O(5), displays a trans-configuration with respect to the C=N double bond. The mol-ecule is twisted, the dihedral angle between the mean planes of the two benzene rings being 18.70 (12)°. The nitro, meth-oxy and acetyl groups are oriented at 80.70 (11), 35.2 (2) and 72.35 (10)°, respectively, to the benzene ring to which they are bonded. The crystal structure is stabilized by weak C-H⋯O hydrogen-bonding contacts.

摘要

标题化合物C(17)H(15)ClN(2)O(5)相对于C=N双键呈现反式构型。分子呈扭曲状，两个苯环平均平面之间的二面角为18.70 (12)°。硝基、甲氧基和乙酰基分别与其相连的苯环呈80.70 (11)°、35.2 (2)°和72.35 (10)°的取向。晶体结构通过弱C-H⋯O氢键接触得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4521/3274996/2ff558ec8511/e-68-0o303-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4521/3274996/14bafd66dcd3/e-68-0o303-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4521/3274996/2ff558ec8511/e-68-0o303-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4521/3274996/14bafd66dcd3/e-68-0o303-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4521/3274996/2ff558ec8511/e-68-0o303-fig2.jpg

相似文献

1
4-[(E)-(3-Chloro-4-methyl-phen-yl)imino-meth-yl]-2-methoxy-3-nitro-phenyl acetate.4-[(E)-(3-氯-4-甲基苯基)亚氨基甲基]-2-甲氧基-3-硝基苯基乙酸酯
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o303. doi: 10.1107/S1600536811055590. Epub 2012 Jan 7.
2
(E)-1-(3-Methoxy-phen-yl)ethanone 4-nitro-phenyl-hydrazone.（E）-1-（3-甲氧基苯基）乙酮4-硝基苯腙
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):o1341. doi: 10.1107/S1600536808018618.
3
7-Meth-oxy-1-{[(Z)-2-nitro-phenyl-imino](phen-yl)meth-yl}-2-naphthol chloro-form monosolvate.7-甲氧基-1-{[(Z)-2-硝基苯基亚氨基](苯基)甲基}-2-萘酚氯仿单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):o3283. doi: 10.1107/S1600536810048002.
4
4-{2-Meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]phen-oxy}phthalonitrile.4-{2-甲氧基-6-[(4-甲基苯基)亚氨基甲基]苯氧基}邻苯二甲腈
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 30;65(Pt 5):o1172. doi: 10.1107/S1600536809015402.
5
(E)-3-(3-Chloro-phen-yl)-1-(4-methoxy-phen-yl)prop-2-en-1-one.（E）-3-（3-氯苯基）-1-（4-甲氧基苯基）丙-2-烯-1-酮
Acta Crystallogr Sect E Struct Rep Online. 2010 May 15;66(Pt 6):o1346-7. doi: 10.1107/S1600536810017150.
6
3-(4-Chloro-phen-oxy)-1-(4-meth-oxy-phen-yl)-4-(4-nitro-phen-yl)azetidin-2-one.3-（4-氯苯氧基）-1-（4-甲氧基苯基）-4-（4-硝基苯基）氮杂环丁烷-2-酮
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1101-2. doi: 10.1107/S1600536811013018. Epub 2011 Apr 13.
7
2-[(E)-2-(4-Chloro-phen-yl)ethen-yl]-1-methyl-pyridinium 4-methoxy-benzene-sulfonate.2-[(E)-2-(4-氯苯基)乙烯基]-1-甲基吡啶鎓 4-甲氧基苯磺酸盐
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):o1549-50. doi: 10.1107/S1600536809021679.
8
2-Bromo-4-chloro-6-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.2-溴-4-氯-6-[(E)-(2-氯苯基)亚氨基甲基]苯酚
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o667. doi: 10.1107/S1600536809007181.
9
2-{(E)-[(3-Iodo-4-methyl-phen-yl)imino]-meth-yl}-4-(trifluoro-meth-oxy)phenol.2-{(E)-[(3-碘-4-甲基苯基)亚氨基]甲基}-4-(三氟甲氧基)苯酚
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2148. doi: 10.1107/S1600536812026876. Epub 2012 Jun 20.
10
2-[(E)-(2-Amino-phen-yl)imino-meth-yl]-5-(dimethyl-amino)phenol.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):o1232. doi: 10.1107/S1600536809015773.

引用本文的文献

1
Crystal structure and Hirshfeld surface analysis of ()-2,4-di--butyl-6-[(3-chloro-4-methyl-phenyl-imino)-meth-yl]phenol.（）-2,4-二-叔丁基-6-[(3-氯-4-甲基-苯基亚氨基)-甲基]苯酚的晶体结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2018 Nov 30;74(Pt 12):1887-1890. doi: 10.1107/S2056989018016377. eCollection 2018 Dec 1.

本文引用的文献

1
(E)-N-[4-(Methyl-sulfon-yl)benzyl-idene]aniline.（E）-N-[4-（甲基磺酰基）亚苄基]苯胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):o18. doi: 10.1107/S1600536809050983.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.