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二溴化[(S)-2-(吡咯烷-2-基)-1H-苯并咪唑]锌(II)

Dibromido[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]zinc(II).

作者信息

Dai Wei, Fu Da-Wei

机构信息

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 9;64(Pt 8):m1016. doi: 10.1107/S1600536808019168.

DOI:10.1107/S1600536808019168
PMID:21203009
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961939/
Abstract

The title compound, [ZnBr(2)(C(11)H(13)N(3))], was synthesized by hydro-thermal reaction of ZnBr(2) and (S)-2-(pyrrolidin-2-yl)-1H-benzimidazole. The Zn(II) atom has a distorted tetra-hedral geometry and is coordinated by two N atoms from the chelating organic ligand and two terminal Br(-) anions. In the crystal structure, mol-ecules are linked into a chain along the [101] direction by N-H⋯Br and C-H⋯Br hydrogen bonds.

摘要

标题化合物[ZnBr₂(C₁₁H₁₃N₃)]通过ZnBr₂与(S)-2-(吡咯烷-2-基)-1H-苯并咪唑的水热反应合成。Zn(II)原子具有扭曲的四面体几何构型，由螯合有机配体的两个N原子和两个末端Br⁻阴离子配位。在晶体结构中，分子通过N-H⋯Br和C-H⋯Br氢键沿[101]方向连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/868a/2961939/b2dede9afafc/e-64-m1016-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/868a/2961939/9ebb767969fc/e-64-m1016-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/868a/2961939/b2dede9afafc/e-64-m1016-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/868a/2961939/9ebb767969fc/e-64-m1016-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/868a/2961939/b2dede9afafc/e-64-m1016-fig2.jpg

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2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Dielectric anisotropy of a homochiral trinuclear nickel(II) complex.
J Am Chem Soc. 2007 May 2;129(17):5346-7. doi: 10.1021/ja0701816. Epub 2007 Apr 12.
二甲基铵双（4-甲基吗啉-4-鎓）四氯锌酸盐
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m1009. doi: 10.1107/S1600536811025049. Epub 2011 Jun 30.
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Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1555. doi: 10.1107/S1600536811019799. Epub 2011 May 28.
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Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):o3296. doi: 10.1107/S1600536810048208.
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