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二溴{2-[(4-氟苯基)亚氨基甲基]吡啶-κ(2)N,N'}锌

Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-κ(2)N,N'}zinc.

作者信息

Dehghanpour Saeed, Mahmoudi Ali

机构信息

Department of Chemistry, Islamic Azad University, Karaj, Iran.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1113. doi: 10.1107/S1600536812031091. Epub 2012 Jul 25.

DOI:10.1107/S1600536812031091
PMID:22904765
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414158/
Abstract

In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49 (1)°. In the crystal, weak C-H⋯F and C-H⋯Br hydrogen bonds are observed.

摘要

在标题配合物[ZnBr₂(C₁₂H₉FN₂)]中，Zn(II)原子具有一个扭曲的四面体Br₂N₂配位球。有机配体是双齿的，通过两个亚胺N原子与Zn(II)原子配位。苯环和吡啶环以10.49 (1)°的二面角取向。在晶体中，观察到弱的C-H⋯F和C-H⋯Br氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4df/3414158/fd435b6bb3f6/e-68-m1113-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4df/3414158/d7f3e8871572/e-68-m1113-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4df/3414158/fd435b6bb3f6/e-68-m1113-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4df/3414158/d7f3e8871572/e-68-m1113-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4df/3414158/fd435b6bb3f6/e-68-m1113-fig2.jpg

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本文引用的文献

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Dibromido{2-[(4-nitro-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).二溴化{2-[(4-硝基苯基)亚氨基甲基]吡啶-κN,N'}锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1556. doi: 10.1107/S1600536811042231. Epub 2011 Oct 22.
2
Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).二溴{2-[(4-溴苯基)亚氨基甲基]吡啶-κN,N'}锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m890. doi: 10.1107/S1600536809025653.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.