二溴{2-[(4-氟苯基)亚氨基甲基]吡啶-κ(2)N,N'}锌
Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-κ(2)N,N'}zinc.
作者信息
Dehghanpour Saeed, Mahmoudi Ali
机构信息
Department of Chemistry, Islamic Azad University, Karaj, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1113. doi: 10.1107/S1600536812031091. Epub 2012 Jul 25.
Abstract
In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49 (1)°. In the crystal, weak C-H⋯F and C-H⋯Br hydrogen bonds are observed.
摘要
在标题配合物[ZnBr₂(C₁₂H₉FN₂)]中，Zn(II)原子具有一个扭曲的四面体Br₂N₂配位球。有机配体是双齿的，通过两个亚胺N原子与Zn(II)原子配位。苯环和吡啶环以10.49 (1)°的二面角取向。在晶体中，观察到弱的C-H⋯F和C-H⋯Br氢键。
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